253334-40-6

Basic information

• Product Name: N¹,N²-di-p-tolylbenzene-1,2-diamine
• Synonyms: N¹,N²-di-p-tolylbenzene-1,2-diamine
• CAS NO: 253334-40-6
• Molecular Weight: 288.392
• Mol File: 253334-40-6.mol

Chemical Properties

• CAS DataBase Reference: N¹,N²-di-p-tolylbenzene-1,2-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: N¹,N²-di-p-tolylbenzene-1,2-diamine(253334-40-6)
• EPA Substance Registry System: N¹,N²-di-p-tolylbenzene-1,2-diamine(253334-40-6)

Safety Data

• Hazardous Substances Data: 253334-40-6(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 765-87-7 cyclohexane-1,2-dione 
• 822-87-7 2-Chlorocyclohexanone 
• 13482-23-0 4-methoxycyclohexanone 
• 108-94-1 cyclohexanone 
• 95-50-1 1,2-dichloro-benzene 
• 106-38-7 para-bromotoluene 
• 95-54-5 1,2-diamino-benzene 

Downstream Products

• 1428798-66-6 C₂₁H₁₉N₂⁽¹⁺⁾*Cl^(1-) 

Relevant articles and documents

Iodine-catalyzed synthesis of N, N ′-diaryl-o-phenylenediamines from cyclohexanones and anilines using DMSO and O2 as oxidants

A novel I2-catalyzed cross-dehydrogenative aromatization of cyclohexanones and anilines to synthesize N,N′-diaryl-o-phenylenediamines has been unprecedentedly developed with dimethyl sulfoxide and oxygen employed as mild terminal oxidants. To prove the rationality of the two separate dehydration steps of the proposed mechanism, a resulting I2-catalyzed cross-dehydrogenative aromatization of cyclohexenones and anilines to synthesize diarylamines has also been reported.

Synthesis of o-Arylenediamines through Elemental Sulfur-Promoted Aerobic Dehydrogenative Aromatization of Cyclohexanones with Arylamines

Herein, the first elemental sulfur-promoted aerobic dehydrogenative aromatization of cyclohexanones is described that provides novel access to synthetically useful o-arylenediamines. This protocol complements previous palladium- A nd iodine-catalyzed diarylamine formation from cyclohexanones and anilines.

Diversity of the quaternary ammonium salt of the imidazole aryl and and its preparation method and application

The present invention discloses a diverse arylimidazole quaternary ammonium salt, a preparation method and an application thereof. The diverse arylimidazole quaternary ammonium salt is a compound represented by a formula (L-n'). The diverse arylimidazole quaternary ammonium salt has the following beneficial effects that: the diverse arylimidazole quaternary ammonium salt can be prepared through the one-pot method and is not prepared in a glove box, the raw material (aliphatic or aromatic imine) is subjected to the reaction, the yield is 78-94%, and the target product with high optical purity dr of more than 98:2 is obtained. According to the present invention, operations can be simplified, the yield can be increased, importantly an application range of the compound is expanded, and wide versatility is provided.

Facial and practical synthesis of benzimidazole-based N-heterocyclic carbenes

An efficient synthesis of benzimidazole-based N-heterocyclic carbenes has been developed. The key step in this synthetic methodology was a one-pot protocol for the synthesis of N,N′-diarylaryldiamines starting from aryldiamine and aryl halides.

Materials for Organic Electroluminescence Devices

The present invention relates to compounds containing a moiety of the formula (1) and to the use thereof in organic electroluminescent devices and to organic electroluminescent devices which comprise compounds of this type.

An efficient palladium-catalysed amination of aryl chlorides in presence of 1,3-bis-(2,6-diisopropylphenyl)imidazolinium chloride

1,3-bis-(2,6-diisopropylphenyl)imidazolinium chloride (SIPr·HCl), a precursor for an N-heterocyclic carbene, was examined as a pro-ligand in C-N coupling reactions. Thus SIPr·HCl associated with a palladium catalyst was found to be efficient for the amination of aryl chlorides under mild conditions.