25357-81-7Relevant academic research and scientific papers
Cationic hydrophilic siloxanyl monomers
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, (2008/06/13)
The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain cationic monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices. Such properties include the ability to extract the polymerized medical devices with water. This avoids the use of organic solvents as is typical in the art. The polymeric compositions comprise polymerized cationic hydrophilic siloxanyl monomers.
Process for making a silylisocyanurate
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, (2008/06/13)
This invention provides a process for making a silylorganocarbamate or a silylisocyanurate which process comprises reacting an aminosilane with a dialkyl carbonate, diaryl carbonate or a mixture thereof in the presence of a basic catalyst to obtain the silylorganocarbamate; optionally, neutralizing the basic catalyst and residual aminosilane with a neutralizing agent; and adding a cracking catalyst and heating at subatmospheric pressure to obtain the silylisocyanurate; or heating a silylorganocarbamate at a temperature sufficient for dissociation of the carbamate at subatmospheric pressure in the presence of a cracking catalyst and a timerization catalyst to obtain a silylisocyanurate.
TRANSETHERIFICATION OF (AMINOPROPYL)TRIETHOXYSILANE ISOMERS WITH TRIMETHYLSILANOL
Kovyazin, V. A.,Kopylov, V. M.
, p. 694 - 696 (2007/10/02)
Decrease in the distance between the nitrogen and silicon atoms in the change from the γ to the β isomer in (aminopropyl)triethoxysilane leads to a considerable rise in the reactivity of the ethoxy groups in the transetherification reaction with trimethylsilanol.
Silicone-compatible phthalocyanine dyestuffs
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, (2008/06/13)
Phthalocyanine dyestuffs containing the tris(trimethylsilyloxy)silylalkylamino group, EQU1 where R1 is H or lower alkyl are produced and are found to be compatible with cured silicone polymers.
