253782-99-9

Upstream product

• 16858-01-8 tris[(2-pyridylmethyl)amine] 
• 832737-81-2 2-chloro-1,3-bis(4′-methyl-phenyl)-1,3-propanedione 
• 4571-27-1 2-chloro-1,3-diphenyl-propane-1,3-dione 
• 99038-25-2 [meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride 
• 147186-13-8 {(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate 
• 108-88-3 toluene 

Relevant academic research and scientific papers

Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: Anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analo

Copper-Dioxygen Reactivity Involved in the Formation of μ-oxoIII-O-CuIIL>+ Heterodinuclear Complexes (por = porphyrinate, L = tetradentate ligand), and Novel Synthesis of Square-Planar FeII(por) Species

In the reaction of FeII(por) species with I(MeCN)>+ and O2 to give μ-oxoIII-O-CuIIL>+ 3 (por = porphyrinate, L = tetradentate ligand), copper-dioxygen adducts or their decomposition products must be present, otherwise III-OH> or III-O-FeIII(por)> products appear; a novel synthesis of square-planar FeII(por) is also described.