25540-73-2

Basic information

• Product Name: 2,2-DIMETHYL-1-(1-NAPHTHYL)-1-PROPANONE
• Synonyms: 2,2-DIMETHYL-1-(1-NAPHTHYL)-1-PROPANONE
• CAS NO: 25540-73-2
• Molecular Formula: C₁₅H₁₆O
• Molecular Weight: 212.29
• Mol File: 25540-73-2.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,2-DIMETHYL-1-(1-NAPHTHYL)-1-PROPANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-DIMETHYL-1-(1-NAPHTHYL)-1-PROPANONE(25540-73-2)
• EPA Substance Registry System: 2,2-DIMETHYL-1-(1-NAPHTHYL)-1-PROPANONE(25540-73-2)

Safety Data

• Hazardous Substances Data: 25540-73-2(Hazardous Substances Data)

Upstream product

• 941-98-0 1'-naphthacetophenone 
• 71-43-2 benzene 
• 594-19-4 tert.-butyl lithium 
• 879-18-5 naphthalene-1-carbonic acid chloride 
• 90-11-9 1-Bromonaphthalene 
• 61838-78-6 2-methyl-1-(1-naphthalenyl)-1-propanone 
• 74-88-4 methyl iodide 
• 91-20-3 naphthalene 
• 3282-30-2 pivaloyl chloride 
• 630-18-2 tert-butyl isocyanide 
• 703-55-9 1-naphthylmagnesiumbromide 
• 79722-74-0 2-<<2,2-dimethyl-1-(1-naphthyl)propylidene>amino>-2,4,4-trimethylpentane 

Downstream Products

• 91-20-3 naphthalene 
• 754-10-9 2,2-dimethylpropionamide 

Relevant articles and documents

Configurational and conformational NMR study of enantiopure 2,2-dimethyl-1-(1-naphthyl)propanol via its carbamate derivatives

2,2-Dimethyl-1-(1-naphthyl)propanol was synthesized and the corresponding enantiomers were isolated by chiral HPLC. These enantiomers gave diastereoisomeric carbamates by reaction with (S)-(-)-1-phenylethylisocyanate, which were studied by NMR. The comparison of NMR data and molecular mechanics calculations allowed us to determine the absolute configuration of corresponding alcohols. Finally, x-ray results were in agreement with the absolute configuration proposed from the NMR spectra. Copyright

Chiral phosphoric acid catalyzed asymmetric transfer hydrogenation of bulky aryl ketones with ammonia borane

An asymmetric transfer hydrogenation of bulky aryl ketones with ammonia borane was successfully realized with chiral phosphoric acid (CPA) as catalyst and water as additive. A variety of optically active secondary alcohols were obtained in good to high yi

Ultrasound assisted Friedel-Crafts acylation of aromatics using ferric sulphate as catalyst

The use of ultrasound in the acylation reactions of various aromatics and polyaromatics with different acyl chlorides, in the presence of catalytic amount of ferric sulphate at room temperature, gives good yields of the respective ketones with a short reaction time. A facile and simple synthesis of various aromatic ketones using Friedel-Crafts acylation has been established from the corresponding acid chlorides and aromatic or polyaromatic compounds, respectively under mild reaction conditions with shorter reaction times (30-45 min) and in reasonable yields. This method offers the advantage of low cost and ease of purification of the products because of the small amount of ferric sulphate used in these reactions.