25541-57-5

Basic information

• Product Name: METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-BETA-D-GLUCOPYRANOSIDE
• Synonyms: METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-BETA-D-GLUCOPYRANOSIDE;METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-SS-D-GLUCOPYRANOSIDE
• CAS NO: 25541-57-5
• Molecular Formula: C₁₄H₁₇NO₇
• Molecular Weight: 311.288
• Mol File: 25541-57-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 510.8±50.0 °C(Predicted)
• Appearance: /
• Density: 1.40±0.1 g/cm3(Predicted)
• PKA: 3.27±0.70(Predicted)
• CAS DataBase Reference: METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-BETA-D-GLUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-BETA-D-GLUCOPYRANOSIDE(25541-57-5)
• EPA Substance Registry System: METHYL-4,6-O-BENZYLIDENE-3-DEOXY-3-NITRO-BETA-D-GLUCOPYRANOSIDE(25541-57-5)

Safety Data

• Hazardous Substances Data: 25541-57-5(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 25541-58-6 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-erythro-hex-2-enopyranoside 
• 140-29-4 phenylacetonitrile 
• 18604-56-3 methyl 2-O-acetyl-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-glucopyranoside 

Relevant articles and documents

DENITRATION OF CARBOHYDRATE α-NITROEPOXIDES BY NUCLEOPHILES

Several nucleophiles were separately treated with methyl and phenyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside, to give 2-substituted aldos-3-ulose derivatives.In the latter case, the subsequent β-elimination of the aglyconic phenyl

REACTIONS OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-NITRO α- AND-β-D-ERYTHRO-HEX-2-ENOPYRANOSIDES WITH PHENYLACETONITRILE: PREPARATION AND STRUCTURAL DETERMINATION OF ADDUCTS AND AN ISOXAZOLE DERIVATIVE

Treatment of methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-α-D-erythro-hex-2-enopyranoside with phenylacetonitrile afforded adducts having the D-manno (2 and 3) and D-gluco configurations (4 and 5), the isoxazole 6, the cyano alkene 7, and the nitro alcoho