25558-12-7

Basic information

• Product Name: 2-(benzylideneamino)-1-phenylethan-1-ol
• Synonyms: 2-(benzylideneamino)-1-phenylethan-1-ol
• CAS NO: 25558-12-7
• Molecular Weight: 225.29
• Mol File: 25558-12-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-(benzylideneamino)-1-phenylethan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzylideneamino)-1-phenylethan-1-ol(25558-12-7)
• EPA Substance Registry System: 2-(benzylideneamino)-1-phenylethan-1-ol(25558-12-7)

Safety Data

• Hazardous Substances Data: 25558-12-7(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 7568-93-6 2-Amino-1-phenylethanol 
• 57402-97-8 N-<(trimethylsilyl)methyl>benzaldimine 

Downstream Products

• 22020-69-5 oxytriphine 
• 102488-25-5 cis-3-phenoxy-4-phenyl-1-(2'-phenyl-2'-tert-butyldimethylsiloxyethyl)azetidin-2-one 
• 97934-56-0 cis-3-phenoxy-4-phenyl-1-(2'-phenyl-2'-hydroxyethyl)azetidin-2-one 
• 102488-27-7 cis-3-phenoxy-4-phenyl-1-(2'-phenyl-2'-oxoethyl)azetidin-2-one 
• 102488-30-2 N-(2'-phenyl-2'-tert-butyldimethylsiloxyethyl)-2-phenylimine 
• 7568-93-6 2-Amino-1-phenylethanol 
• 51096-49-2 2-benzylamino-1-phenyl-ethanol 
• 102488-29-9 [1-Phenyl-meth-(E)-ylidene]-(2-phenyl-2-trimethylsilanyloxy-ethyl)-amine 

Relevant articles and documents

Use of Hypervalent Iodine in the Synthesis of Isomeric Dihydrooxazoles

[Figure not available: see fulltext.] A convenient synthesis of 2- and/or 3-oxazolines has been developed depending on the structure and stereochemistry of the starting amino alcohol. PhI(OAc)2 acted as oxidant on the intermediate imine, as sup

SYNTHETIC APPLICATIONS OF CHROMIUM(VI) REAGENTS IN COMBINATION WITH CHLOROTRIMETHYLSILANE

The synthetic utility of chromium(VI) reagents together with chlorotrimethylsilane, as new oxidizing systems, is described.Pyridinium dichromate (PDC) in combination with chlorotrimethylsilane oxidizes tert-butyldimethylsilyl ethers in good to excellent yields.Trimethylsilyl chlorochromate, a new chromium(VI) reagent, also was found efficient for this oxidative-deprotection method.These reagents were applied to the oxidation of some N-(2-phenyl-2-hydroxyethyl)azetidin-2-ones as well as N-(2-phenyl-2-trialkylsiloxy)azetidin-2-ones into their corresponding carbonyl compounds, key intermediates for N-unsubstituted β-lactams.Oxidation of hydroquinones and protected trialkylsilyl hydroquinones was also described.Protection of hydroquinones by means of the tert-butyldimethylsilyl group was achieved by using the readily available tert-butyldimethylchlorosilane (TBDMCS) and 1,8-diazabicycloundec-7-ene (DBU) as base, which avoids the use of sophisticated and (or) sensitive reagents.