255711-84-3

Upstream product

• 18689-32-2 diethyl (E)-1-propenylphosphonate 
• 98-80-6 phenylboronic acid 
• 40962-69-4 (E)-diethyl (2-phenylprop-1-en-1-yl)phosphonate 
• 51876-00-7 1-diethoxyphosphonyl-2-phenylprop-2-ene 
• 1660-94-2 Tetraethyl methylenediphosphonate 
• 98-86-2 acetophenone 
• 5954-65-4 diethyl ester of 2-methylvinylphosphonic acid 
• 78462-97-2 diethyl (Z)-(2-phenylprop-1-en-1-yl)phosphonate 
• 3262-89-3 triphenylboroxine 

Downstream Products

• 255711-91-2 ((S)-2-Phenyl-propyl)-phosphonic acid diphenyl ester 
• 255711-93-4 C₂₂H₂₀ 
• 942517-54-6 (S)-(+)-1,1,3-triphenylbut-1-ene 

Relevant academic research and scientific papers

Rhodium-catalyzed enantioselective hydrogenation of unsaturated phosphonates by ClickFerrophos ligands

Newly developed ClickFerrophos II ligands were applied in the hydrogenation of α,β-unsaturated phosphonates. The use of a rhodium/ClickFerrophos II catalyst was examined in the hydrogenation of functionalized α,β-unsaturated phosphonates and was revealed

Cu-catalyzed asymmetric conjugate reduction of β-substituted α,β-unsaturated phosphonates: an efficient synthesis of optically active β-stereogenic alkylphosphonates

A series of chiral alkylphosphonates bearing β-stereogenic center were synthesized in good enantioselectivities (up to 95% ee) via the CuH-catalyzed asymmetric conjugate reduction of β-substituted α,β-unsaturated phosphonates under optimal conditions usin

Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes

Enantiodivergent, catalytic reduction of activated alkenes relays stereochemical information encoded in the antipodal chiral catalysts to the pro-chiral substrate. Although powerful, the strategy remains vulnerable to costs and availability of sourcing bo

Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated hosphonates

A series of chiral ferrocenyl diphosphine ligands (ImiFerroPhos ligands) has been applied to the hydrogenation of β-substituted α,β- unsaturated phosphonates to generate a range of optically active β-substituted alkylphosphonates in good yields with good

Enantioselective synthesis of optically active alkylphosphonates via Rh-catalyzed asymmetric hydrogenation of β-substituted α,β- unsaturated phosphonates

The Rh-catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates using (Sc,S p)-WalPhos as the chiral ligand is reported, in which a wide range of optically active β-substituted alkylphosphonates were obtained

Highly enantioselective Rh-catalyzed hydrogenation of β,γ- unsaturated phosphonates with chiral ferrocene-based monophosphoramidite ligands

(Chemical Equation Presented) An enantioselective synthesis of chiral alkylphosphonates bearing a β-stereogenic center, based on the Rh-catalyzed asymmetric hydrogenation of corresponding β-substituted β,γ-unsaturated phosphonates with a ferrocene-based monophosphoramidite ligand under the mild hydrogenation conditions, was developed, in which an ee value of up to 98% was obtained.

Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands

A series of chiral β-substituted alkane-phosphonates was synthesized in high enantioselectivities via the first rhodium-catalyzed asymmetric hydrogenation of the corresponding β-substituted-α,β-unsaturated phosphonates using a ferrocene-derived monophosphoramidite ligand, with which up to 99.5% ee have been achieved for the hydrogenation of (E)-substrates and 98.0% ee for (Z)-substrates.