25594-66-5

Basic information

• Product Name: Benzeneacetonitrile, a-acetyl-3-methoxy-
• CAS NO: 25594-66-5
• Molecular Formula: C11H11NO2
• Molecular Weight: 189.214
• Mol File: 25594-66-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzeneacetonitrile, a-acetyl-3-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, a-acetyl-3-methoxy-(25594-66-5)
• EPA Substance Registry System: Benzeneacetonitrile, a-acetyl-3-methoxy-(25594-66-5)

Safety Data

• Hazardous Substances Data: 25594-66-5(Hazardous Substances Data)

Upstream product

• 19924-43-7 3-methoxyphenylacetonitrile 
• 141-78-6 ethyl acetate 

Downstream Products

• 1369597-18-1 5-methoxy-1-(3-methoxyphenyl)-2-methyl-1H-indene-1,3-dicarbonitrile 
• 1346260-40-9 (E)-2-(methoxyimino)-1-(3-methoxyphenyl)propan-1-one 
• 10557-22-9 1-(3-methoxyphenyl)propane-1,2-dione 
• 76106-58-6 4-phenyl-1-(3-tetrahydropyranyloxyphenyl)but-3-en-2-one 
• 76106-52-0 5,5-dimethyl-1-(3-tetrahydropyranyloxyphenyl)hex-3-en-2-one 
• 76106-51-9 m-tetrahydropyranyloxyphenylacetone 
• 76106-62-2 1-(3-methoxyphenyl)-4-phenylbut-3-en-2-one 
• 76106-56-4 1-(3-methoxyphenyl)-1,5,5-trimethylhex-3-en-2-one 
• 76106-59-7 1-(3-hydroxyphenyl)-4-phenylbut-3-en-2-one 
• 76106-55-3 1-(3-methoxyphenyl)-5,5-dimethylhex-3-en-2-one 
• 64479-84-1 1-(3-hydroxyphenyl)propan-2-one 
• 157835-01-3 N-acetyl-2-(3-methoxyphenyl)-2-(2-methyldithiolan-2-yl)propylamine 
• 157834-97-4 2-(3-methoxyphenyl)-3-(1,4-dithiapentyl)-but-3-enyl-2-cyanide 
• 157834-99-6 2-(3-methoxyphenyl)-2-(2-methyldithiolan-2-yl)-propionitrile 

Relevant articles and documents

Stereoselective C?C Oxidative Coupling Reactions Photocatalyzed by Zwitterionic Ligand Capped CsPbBr3 Perovskite Quantum Dots

Semiconductor quantum dots (QDs) have attracted tremendous attention in the field of photocatalysis, owing to their superior optoelectronic properties for photocatalytic reactions, including high absorption coefficients and long photogenerated carrier lifetimes. Herein, by choosing 2-(3,4-dimethoxyphenyl)-3-oxobutanenitrile as a model substrate, we demonstrate that the stereoselective (>99 %) C?C oxidative coupling reaction can be realized with a high product yield (99 %) using zwitterionic ligand capped CsPbBr3 perovskite QDs under visible light illumination. The reaction can be generalized to different starting materials with various substituents on the phenyl ring and varied functional moieties, producing stereoselective dl-isomers. A radical mediated reaction pathway has been proposed. Our study provides a new way of stereoselective C?C oxidative coupling via a photocatalytic means using specially designed perovskite QDs.

Intramolecular Alkylation of Phenols. Part 4. Base-catalysed Cyclisation of Phenolic Enones. Scope and Limitations

The phenolic enones (4), (5), (8), (9), and (13) cyclise readily under acidic conditions.However, neither these nor the thio-substituted phenols (11a), (13a), (14a), and (15a) closed under basic conditions.Involvement of unfavourable equilibria is disproved.Comparison is made with related successful cyclisations of the saturated ketone (38) and aldehyde (39).Preliminary results suggest that strict stereo-electronic requirements are necessary for enone ring closure and that these conditions are not met in base-catalysed 5-Endo- and 6-Endo-Trigonal ring closures of the phenols of general type (2; n=0 and n=1).