25628-11-9

Basic information

• Product Name: phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
• Synonyms: Phenyl 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonate
• CAS NO: 25628-11-9
• Molecular Formula: C₁₀H₅F₉O₃S
• Molecular Weight: 376.1955
• Mol File: 25628-11-9.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 265.5°C at 760 mmHg
• Flash Point: 114.4°C
• Density: 1.613g/cm³
• Vapor Pressure: 0.015mmHg at 25°C
• Refractive Index: 1.403
• CAS DataBase Reference: phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate(25628-11-9)
• EPA Substance Registry System: phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate(25628-11-9)

Safety Data

• Hazardous Substances Data: 25628-11-9(Hazardous Substances Data)

Usage

General Description

Phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate is a chemical compound that belongs to the class of sulfonates. It is a nonafluorobutane derivative with a phenyl group attached to the sulfur atom. phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate is widely used as a surfactant and wetting agent in various industries due to its strong hydrophobic and oleophobic properties. It is particularly effective in reducing surface tension and facilitating the spread of liquids on surfaces. Additionally, phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate is known for its ability to enhance the performance of coatings, adhesives, and cleaning products by improving their wetting and spreading characteristics.

Upstream product

• 375-72-4 Nonafluorobutanesulfonyl fluoride 
• 139-02-6 sodium phenoxide 
• 29420-49-3 potassium nonaflate 
• 98-80-6 phenylboronic acid 
• 1864-94-4 phenyl formate 
• 62-53-3 aniline 
• 1529-17-5 phenyltrimethylsilyl ether 
• 108-95-2 phenol 
• 36913-91-4 nonaflyl anhydride 

Downstream Products

• 415708-08-6 exo-2-phenylbicyclo[2.2.1]heptane 
• 139152-86-6 (1R,2R)-(-)-exo-2-phenylbicyclo[2.2.1]heptane 
• 199465-44-6 4-iodophenyl nonaflate 
• 321970-34-7 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonic acid 4-bromophenyl ester 
• 32848-23-0 para-nitrophenyl perfluorobutanesulfonate 
• 32848-24-1 ethyl 4-(((nonafluorobutyl)sulfonyl)oxy)benzoate 
• 16967-02-5 1-phenyl-1-octyne 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 103-26-4 Methyl cinnamate 
• 6919-61-5 N-methoxy-N-methylbenzamide 
• 791-28-6 Triphenylphosphine oxide 
• 37391-19-8 3-methyl-3-phenylindoline 
• 2189-60-8 Octylbenzene 
• 351186-42-0 N‐morpholinobenzenesulfonamide 

Relevant articles and documents

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Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

Herein we present a Bi-catalyzed cross-coupling of arylboronic acids with perfluoroalkyl sulfonate salts based on a Bi(III)/Bi(V) redox cycle. An electron-deficient sulfone ligand proved to be key for the successful implementation of this protocol, which allows the unusual construction of C(sp2)-O bonds using commercially available NaOTf and KONf as coupling partners. Preliminary mechanistic studies as well as theoretical investigations reveal the intermediacy of a highly electrophilic Bi(V) species, which rapidly eliminates phenyl triflate.

Aryl formate as bifunctional reagent: Applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO

After decades of development, carbonylation reactions have become one of the most powerful tools in modern organic synthesis. However, the requirement of CO gas limits the applications of such reactions. Reported herein is a versatile and practical protocol for carbonylative reactions which rely on the cooperation of phenyl formate and nonaflate, and the generation of CO in situ. This protocol has a high functional-group tolerance and could be applied in carbonylations with C, N, and, O nucleophiles. The corresponding amides, alkynones, furanones, and aryl benzoates were synthesized in good yields. Transformers: A versatile and practical protocol for carbonylation reactions involve the cooperation of phenyl formate and nonaflate with generation of CO in situ. This protocol has a high functional-group tolerance and could be applied in carbonylative couplings with C, N, and O nucleophiles. The corresponding amides, alkynones, furanones, and aryl benzoates were synthesized in good yield.