25635-39-6Relevant academic research and scientific papers
HOMOLYTIC ALKOXYCARBONYLATION REACTIONS IN TWO-PHASE SYSTEMS, PART II. STUDIES ON THE ETHOXYCARBONYLATION OF SOME SELECTED ?-DEFICIENT N-HETEROAROMATIC SYSTEMS
Heinisch, Gottfried,Loetsch, Gerhard
, p. 5973 - 5977 (1986)
A systematic study on the homolytic substitution of pyridine, quinoline and pyrazine by ethoxycarbonyl radicals was performed.It is demonstrated that under appropriate conditions Minisci-type alkoxycarbonylation reactions can provide convenient access to heteroaromatic monocarboxylic acid esters, like alkyl 2-pyrazinecarboxylates and alkyl 4-alkyl-2-pyridinecarboxylates.
