Tetrahedron p. 5973 - 5977 (1986)
Update date:2022-08-03
Topics:
Heinisch, Gottfried
Loetsch, Gerhard
A systematic study on the homolytic substitution of pyridine, quinoline and pyrazine by ethoxycarbonyl radicals was performed.It is demonstrated that under appropriate conditions Minisci-type alkoxycarbonylation reactions can provide convenient access to heteroaromatic monocarboxylic acid esters, like alkyl 2-pyrazinecarboxylates and alkyl 4-alkyl-2-pyridinecarboxylates.
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