25636-61-7Relevant articles and documents
Facile deprotection of dithioacetals by using a novel 1,4-benzoquinone/cat. NaI system
Inamoto, Kiyofumi,Yamada, Tetsuya,Kato, Sei-Ichi,Kikkawa, Shoko,Kondo, Yoshinori
, p. 9192 - 9199 (2013/10/01)
The combination of 1,4-benzoquinone and a catalytic amount of NaI was found to be effective for the deprotection of dithioacetals. The reactions proceeded efficiently under mild, near-neutral reaction conditions, producing a wide range of aryl and alkyl aldehydes and ketones generally in high yields with good functional group compatibility. The method developed therefore represents a general, facile, and highly applicable approach for deprotecting dithioacetals.
THE REDUCTION OF CYCLIC DISULPHIDES WITH TRIARYLPHOSPHINES IN AQUEOUS ORGANIC SOLVENTS
Salim, A.,Tillett, J. G.
, p. 215 - 222 (2007/10/02)
The kinetics of the reduction of cyclic disulphides with triphenylphosphine have been studied in aqueous ethanol at various temperatures.Solvent effects on the reaction of 4-phenyl-1,2-dithiolane with tris-(4-chlorophenyl) phosphine in a number of aqueous organic solvents have been analysed in terms of the Kirkwood, Y and ENT functions.