256505-80-3Relevant academic research and scientific papers
A pentacoordinated Di-N-carboxamidodithiolato- O-sulfinato-iron(III) complex related to the metal site of nitrile hydratase
Heinrich, Laurent,Li, Yun,Vaissermann, Jacqueline,Chottard, Genevieve,Chottard, Jean-Claude
, p. 3526 - 3528 (1999)
Postcoordination oxidation by dioxygen of one of the thiolate groups in a pentadentate N2S3 ligand results in an iron(III) complex with two N- carboxamido, two thiolato, and one O-sulfinato ligands (see the CAMERON representation). T
Synthesis of polydentate ligands containing amides and thiols for biomimetic metal complexes
Heinrich,Chottard,Li
, p. 1323 - 1333 (2007/10/03)
Three pentadentate "N2S3" and one tetradentate "N2S2" new ligands with "N" = CONH and "S" = SH have been synthesized. The key step is the direct diamide formation from the malonyl diester and the amines in the p
