256510-27-7Relevant academic research and scientific papers
Diastereoselective 1,3-dipolar cycloaddition of nitrilimines to γ-oxygenated α,β-unsaturated enones and esters
Grubert, Lutz,Galley, Guido,Paetzel, Michael
, p. 1137 - 1148 (1996)
The stereochemical outcome of the 1,3-dipolar cycloaddition of nitrilimines to γ-oxygenated α,β-unsaturated enones and esters was investigated. By means of X-ray and NMR analysis the main diastereomers were assigned as the syn-derivatives. Novel enantiomerically pure nitrilimines were included in the investigations but did not influence the stereochemical course of the cycloaddition significantly.
