25691-81-0Relevant articles and documents
Reactivity of 1-deoxy-D-erythro-hexo-2,3-diulose; A key intermediate in the maillard chemistry of hexoses
Voigt, Michael,Glomb, Marcus A.
, p. 4765 - 4770 (2009)
Degradation of 1-deoxyhexo-2,3-diulose, a key intermediate in Maillard chemistry, in the presence of L-alanine under moderate conditions (37 and 50 °C) was investigated. Different analytical strategies were accomplished to cover the broad range of product
Identification and determination of α-dicarbonyl compounds formed in the degradation of sugars
Usui, Teruyuki,Yanagisawa, Satoshi,Ohguchi, Mio,Yoshino, Miku,Kawabata, Risa,Kishimoto, Junko,Arai, Yumi,Aida, Kaoru,Watanabe, Hirohito,Hayase, Fumitaka
, p. 2465 - 2472 (2008/03/27)
The α-dicarbonyl compounds formed in the degradation of glucose and fructose were analyzed by HPLC using 2,3-diaminonaphthalene as derivatizing reagent, and identified as glucosone (GLUCO), 3-deoxyglucosone (3DG), 3-deoxyxylosone (3DX), tetrosone (TSO), triosone (TRIO), 3-deoxytetrosone (3DT), glyoxal (GO), and methylglyoxal (MGO). The results suggest that α-dicarbonyl compounds were formed from glucose via non-oxidative 3-deoxyglucosone formation and oxidative glucosone formation in glucose degradation. In addition, TRIO, GO, and MGO were also formed from glyceraldehyde as intermediate. The α-dicarbonyl compounds might be formed from glucose via these pathways in diabetes.
