256954-13-9Relevant academic research and scientific papers
Technetium and rhenium heterocomplexes containing the diphenylphosphinoferrocenyl fragment
Tisato, Francesco,Refosco, Fiorenzo,Porchia, Marina,Bandoli, Giuliano,Pilloni, Giuseppe,Uccelli, Licia,Boschi, Alessandra,Duatti, Adriano
, p. 772 - 776 (2001)
Reactions of dppf with labile technetium and rhenium precursors such as [M(N)Cl4]- and [M(NPh)Cl3(PPh3)2] yield the monomeric mono-substituted [M(N)Cl2(dppf)] and [M(NPh)Cl3(dppf)] complexes, where the diphosphinoferrocenyl fragment coordinates on the equatorial plane of a distorted square pyramid or of a distorted octahedron, respectively.
Re(V)-oxo-dppf and Re(V)-imido-dppf complexes: Synthesis, structure, and properties of Re(X)Cl3(dppf) (X=O, NPh, N-C6H3-2,6-i-Pr2; Dppf=Fe(η5-C5H4PPh2) 2)
Choi, Nam-Sun,Lee, Soon W.
, p. 226 - 232 (2007/10/03)
Re(V)-imido and Re(V)-oxo complexes containing 1,1′-bis(diphenylphosphino)ferrocene (Fe(η5-C5H4PPh2)2, dppf) were prepared from mer,trans-Re(O)Cl3(PPh3)2 (1), mer,tran
