257288-33-8

Basic information

• Product Name: 8-epi-19,20-di-O-benzyl-puupehenol
• Synonyms: 8-epi-19,20-di-O-benzyl-puupehenol
• CAS NO: 257288-33-8
• Molecular Weight: 510.717
• Mol File: 257288-33-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 8-epi-19,20-di-O-benzyl-puupehenol(CAS DataBase Reference)
• NIST Chemistry Reference: 8-epi-19,20-di-O-benzyl-puupehenol(257288-33-8)
• EPA Substance Registry System: 8-epi-19,20-di-O-benzyl-puupehenol(257288-33-8)

Safety Data

• Hazardous Substances Data: 257288-33-8(Hazardous Substances Data)

Upstream product

• 257288-31-6 11-(2-tert-butyldimethylsilyloxy-4,5-di-benzyloxyphenyl)-8-drimene 
• 189082-99-3 3,4-di-O-benzyl-2-bromo-1-O-tert-butyldimethylsilylbenzenetriol 
• 120951-85-1 1,2-di-O-benzyl-4-O-tert-butyldimethylsilylbenzenetriol 
• 316803-64-2 Acetic acid (1R,2R,4aS,8aS)-1-iodomethyl-2,5,5,8a-tetramethyl-decahydro-naphthalen-2-yl ester 
• 851279-15-7 3,4-di-benzyloxy-6-(7'-drimen-11'-ylidene)-2,4-cyclohexadienone 
• 105426-71-9 (1S,4aS,8aS)-1,4,4a,5,6,7,8,8a-octahydro-2,5,58a-tetramethylnaphtahelene-1-carboxaldehyde 
• 86546-84-1 (5S,8R,10S)-drim-9⁽¹¹⁾-en-8-ol 
• 468-68-8 (-)-drimenol 
• 52617-99-9 (+)-drimane-8,11-diol 
• 27688-86-4 3,4-dibenzyloxyphenol 
• 851279-14-6 4,5-di-O-benzyl-2-bromo-1O-diethylcarbamoylbenzenetriol 
• 851279-13-5 1,2-di-O-benzyl-4-O-diethylcarbamoylbenzenetriol 
• 257288-32-7 2-(8-drimen-11-yl)-4,5-dibenzyloxyphenol 

Relevant articles and documents

First enantiospecific synthesis of the antitumor marine sponge metabolite (-)-15-oxopuupehenol from (-)-sclareol

(Chemical Equation Presented) A new route toward puupehenone-related bioactive metabolites from (-)-sclareol, based on the palladium(II)-mediated diastereoselective cyclization of a drimenylphenol, is described. Utilizing this, the first enantiospecific synthesis of the antitumor and antimalarial (-)-15-oxopuupehenol, together with improved syntheses of (+)-puupehenone, (+)-puupehedione, and (+)-15-cyanopuupehenone, were accomplished.