25741-81-5

Usage

Uses

Used in Organic Synthesis:
(N,N-dimethylmethanamine)(dihydrido)iodoboron is used as a reagent for the preparation of various boron-containing molecules. Its unique structure facilitates the formation of new compounds, making it a valuable tool in the field of organic chemistry.
Used as a Catalyst:
In the chemical industry, (N,N-dimethylmethanamine)(dihydrido)iodoboron is used as a catalyst in certain chemical reactions. Its ability to selectively interact with other molecules makes it an efficient catalyst, enhancing the rate of reactions and improving the overall yield of desired products.
Used in Medical Imaging:
(N,N-dimethylmethanamine)(dihydrido)iodoboron has been studied for its potential use in medical imaging. Its unique properties allow it to be used as a contrast agent, helping to improve the visualization of certain structures within the body.
Used in Cancer Therapy:
In the field of oncology, (N,N-dimethylmethanamine)(dihydrido)iodoboron has been investigated for its potential use in cancer therapy. It has been found to selectively target certain types of cancer cells, making it a promising candidate for the development of targeted cancer treatments. Further research is needed to fully understand its potential and optimize its use in this application.

Upstream product

• 1231953-83-5 trimethylamine borane 
• 75-22-9 trimethylamine-borane 
• 7553-56-2 iodine 
• 10034-85-2 hydrogen iodide 

Downstream Products

• 1135446-18-2 [H₂B(ImMes)2]I 
• 59301-48-3 ammonia-cyanoborane 
• 30353-61-8 trimethylamine-cyanoborane 
• 75-22-9 trimethylamine-borane 

Relevant academic research and scientific papers

Novel boronium salt exhibits substantial antibacterial activity when compared to a commercial quaternary ammonium disinfectant

Commercial disinfectants are routinely used to decontaminate surfaces where microbes are expected and unwelcome. Several disinfectants contain quaternary ammonium salts, or “quats”, all being derived from ammonium. Quaternary alkyl dimethyl benzyl ammonium chloride or bromide disinfectants are widely available. These compounds are effective in reducing or eliminating bacteria on contaminated nonporous surfaces. A unique benzyl derived boronium salt with strong detergent action has been developed. It demonstrated 4-8X greater antibacterial activity against 3 different bacteria when compared to an equal concentration of a commercial quant disinfectant solution containing alkyl dimethyl benzyl ammonium chloride and alkyl dimethyl ethylbenzyl ammonium chloride. Antibacterial effectiveness of each agent was determined by the minimum inhibitory concentration (MIC) method.

Exploiting isolobal relationships to create new ionic liquids: Novel room-temperature ionic liquids based upon (N-alkylimidazole)(amine)BH 2+ "boronium" ions

Readily prepared imidazole-based boronium ions form stable, hydrophobia, room-temperature ionic liquids (RTIL) with unique electronic and spectroscopic characteristics. The Royal Society of Chemistry 2005.

A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments

A general approach for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments has been developed through metathesis reactions between amine chloroborane complexes and potassium salt of trinitromethyl (K[C(NO2)3]). Five covalent and ionic trinitromethyl amine borane complexes have been synthesized in good yields with high purity and it is found that the ionic complex, [H2B(NH3)2][C(NO2)3], might be a promising energetic material on the basis of the investigation of its thermal decomposition behaviour.

BORONIUM-ION-BASED IONIC LIQUIDS AND METHODS OF USE THEREOF

One aspect of the present invention relates to "boronium" ions that are stable, hydrophobic, room-temperature ionic liquids. In certain embodiments, ionic liquids of the instant invention are represented by the formula [XnBY4-n]+(n-1) (n-l)Z-1, wherein X refers to a Lewis base, Y refers to a substituent covalently bonded to boron, Z-1 is a charge diffuse anion, and x is 2, 3 or 4. In certain embodiments, the ionic liquids of the instant invention are of the general type [X2BY2]+1 Tf2N-1, wherein each X is independently a tertiary amine, a N-alkylimidazole or a pyridine; and each B-X bond is a B-N bond.

The kinetics and mechanism of trimethylamine-haloborane hydrolysis

The rates of solvolysis of trimethylamine-monohaloboranes in aqueous dioxane at 25° increase in the series (CH3)3NBH2Cl 3)3NBH2Br 3)3NBH2I. The diiodoborane adduct reacts more slowly than the monoiodo compound but faster than trimethylamine-borane. Only a very slight retardation in rate is observed on substitution of deuterium for hydrogen on boron in the diiodo derivative (kH/kD = 1.1); however, a noticeable solvent isotope effect (kH2O/kD2O = 1.8) is observed for hydrolysis of both the mono- and diiodoborane adducts in 67% aqueous dioxane at 25°. Rates increase with increasing water content of the aqueous dioxane solvent system. No significant effect on rate of acidity is seen for hydrogen ion concentrations as high as 0.3 M or hydroxide ion concentrations up to 0.1 M, nor is the rate appreciably affected by the addition of potassium chloride or potassium iodide up to 0.3 M. The results indicate a mechanism for hydrolysis of the halo compounds quite different from that postulated for amine-BH3 adducts. It is proposed that a rate-determining cleavage of a boron-halogen bond is followed by rapid collapse of an incipient boron(1+) ion. An analogy to nucleophilic substitution reactions in haloborane-amines leading to kinetically stable boronium ions is suggested.