2579-21-7Relevant articles and documents
Decarbopalladation of π-allylpalladium intermediates formed from palladium-catalyzed arylations of 3-allen-1-ols
Oh, Chang Ho,Jung, Seung Hyun,Bang, Su Youn,Park, Dai In
, p. 3325 - 3327 (2007/10/03)
eqution presented Unusual palladium-catalyzed arylative fragmentations of acyclic 3-allen-1-ols were observed. Oxidative addition of Pd(0) to aryl halides would form the arylpalladium halides, which added to the central carbon of allenes via carbopalladation to form the π-allylpalladium intermediates. The π-allylpalladium intermediates would be reductively eliminated via carbon-carbon cleavage to give the arylated dienes and the α-hydroxyalkylpalladium intermediates, which were further reductively eliminated to the corresponding aldehydes.