25798-60-1

Basic information

• Product Name: Benzene, 1-nitro-4-(1-propenyl)- (9CI)
• Synonyms: Benzene, 1-nitro-4-(1-propenyl)- (9CI)
• CAS NO: 25798-60-1
• Molecular Formula: C₉H₉NO₂
• Molecular Weight: 163.17
• Mol File: 25798-60-1.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-nitro-4-(1-propenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-4-(1-propenyl)- (9CI)(25798-60-1)
• EPA Substance Registry System: Benzene, 1-nitro-4-(1-propenyl)- (9CI)(25798-60-1)

Safety Data

• Hazardous Substances Data: 25798-60-1(Hazardous Substances Data)

Upstream product

• 75-07-0 acetaldehyde 
• 636-98-6 p-nitrobenzene iodide 
• 13154-14-8 1-propenylmagnesium bromide 
• 29865-60-9 1-nitro-4-(2-nitropropyl)benzene 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 4231-16-7 1-(p-nitrophenyl)-2-nitro-1-propene 
• 591-87-7 Allyl acetate 
• 51042-50-3 4-nitrobenzyltriphenylarsonium bromide 
• 2767-70-6 (p-nitrobenzyl)triphenylphosphonium bromide 

Downstream Products

• 1734-79-8 3-(4-nitrophenyl)-2-propenal 
• 1205-56-7 2-bromo-1-(4-nitrophenyl)propan-1-one 
• 17931-11-2 5-methyl-4-(4-nitrophenyl)-2-phenylthiazole 
• 6159-25-7 1-<(4-nitro)-phenyl>-1,2-propandione 
• 74026-42-9 2-<4-(4-Nitrophenyl)-1(E),3(E)-butadienyl>-3-phenyloxiran 
• 74026-42-9 2-<4-(4-Nitrophenyl)-1(Z),3(E)-butadienyl>-3-phenyloxiran 
• 74026-46-3 cis-2,3-Dihydro-3-<2-(4-nitrophenyl)vinyl>-2-phenylfuran 
• 7743-31-9 <3-(4-Nitrophenyl)-2-propenyl>triphenylphosphoniumbromid 
• 79750-53-1 (E)-3-(4-nitrophenyl)prop-2-en-1-yl bromide 

Relevant articles and documents

Sequential Acylation/Silylation/Hetero-Claisen Rearrangement of Nitroalkanes for the Synthesis of Protected Hydroxyoxime Derivatives

Sequential acylation-silylation of nitroalkanes leads to O-silylated α-acyloxyoximes in high yields. The first step of the reaction involves deprotonation of nitro compound with sodium hydride promoted by DBU or alcohol/15-crown-5 system followed by treat

Palladium-catalyzed coupling reaction of alkenylgalliums with aryl halides

Treatment of aryl halides with alkenylgallium dichloride, prepared from GaCl3 and alkenylmagnesium bromide, in the presence of a catalytic amount of palladium provided cross-coupling products in good yields.

6- and 8?-Ringschlussreaktionen von 2-Oxaheptatrienyl-Dipolen: Synthese von 3-Vinyl-2,3-dihydrofuranen und 2,3(6,7)-Dihydrooxepinen

The thermally induced ring expansion reactions of several butadienyloxiranes are described.The 3(E)-configurated epoxytrienes 11 are transformed predominantly into cis-3-vinyl-2,3-dihydrofurans 15, the trans-isomers 16 being formed as a minor component only with the derivatives a, c, and h.In contrast, thermolysis of the 3(Z)-butadienyloxiranes 12 leads always to a mixture of fivemembered ring products (15/16) and, additionally, dihyrooxepins (17 and 29, resp.).As mechanism of the ring expansion reactions a multistep sequence is proposed with 2-oxaheptatrienyl dipoles as intermediates, which undergo electrocyclisation with participation of either six or eight electrons leading to dihydrofurans and dihydrooxepins, resp.With relation to 1,7-cyclisation reactions of other extended dipole systems the importance of the stereochemistry in the starting materials is emphasised.