25874-16-2

Basic information

• Product Name: 3,4-di-O-benzoyl-D-arabinal
• Synonyms: 3,4-di-O-benzoyl-D-arabinal
• CAS NO: 25874-16-2
• Molecular Weight: 324.333
• Mol File: 25874-16-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,4-di-O-benzoyl-D-arabinal(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-di-O-benzoyl-D-arabinal(25874-16-2)
• EPA Substance Registry System: 3,4-di-O-benzoyl-D-arabinal(25874-16-2)

Safety Data

• Hazardous Substances Data: 25874-16-2(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 496-61-7 1,5-anhydro-2-deoxy-D-erythro-pent-1-enitol 
• 60426-89-3 2,3,4-tri-O-benzoyl-α-D-arabinopyranosyl bromide 

Downstream Products

• 130794-93-3 1-Acetyl-3,4-dibenzoyl-2-desoxy-β-D-ribopyranose 

Relevant articles and documents

A mild and environmentally benign method for the synthesis of glycals in PEG-600/H2O

Glycals were synthesized via a simple, mild, convenient and environmentally benign procedure, in which protected glycosyl bromides undergo the reductive elimination in the presence of zinc in PEG-600/H2O at room temperature. The glycals were obtained in 75-92% isolated yields.

Total synthesis of (+)-cacospongionolide B

Total synthesis of (+)-cacospongionolide B was achieved. The synthesis involved highly stereoselective C-glycosidation of a glycal derived from D-arabinose with 3-furyl boronic acid in the presence of a palladium catalyst and S-alkyl Suzuki-Miyaura coupling of in situ generated alkylborane prepared by the reaction of vinyl trans-decaMn with alkenyl triflate.