258851-74-0Relevant articles and documents
Ytterbium(III) triflate/TMSCI: Efficient catalyst for imino ene reaction
Yamanaka, Masamichi,Nishida, Atsushi,Nakagawa, Masako
, p. 159 - 161 (2000)
(equation presented) Ytterbium trifluoromethanesulfonate [Yb(OTf)3] catalyzed the imino ene reaction of N-tosyl aldimine with α-methylstyrene to give a homoallylamine in moderate yield. Furthermore, addition of a catalytic amount of chlorotrime
Palladium-Catalyzed Direct Intramolecular C-N Bond Formation: Access to Multisubstituted Dihydropyrroles
Jiang, Bing,Meng, Fei-Fan,Liang, Qiu-Ju,Xu, Yun-He,Loh, Teck-Peng
, p. 914 - 917 (2017/02/26)
A palladium-catalyzed intramolecular amination of alkenes with retention of olefin functionalization was achieved under mild reaction conditions. In the presence of palladium catalyst, the tosyl-protected amine can directly couple with a double bond to provide versatile dihydropyrrole derivatives in moderate to excellent yields.
Imino ene reaction catalyzed by Ytterbium(III) Triflate and TMSCl or TMSOTf
Yamanaka, Masamichi,Nishida, Atsushi,Nakagawa, Masako
, p. 3112 - 3120 (2007/10/03)
A novel combined system of Yb(OTf)3 with TMSCl or TMSOTf catalyzed an imino ene reaction. The reaction of N-tosylbenzaldimine (1) with α-methylstyrene (2) proceeded smoothly to give homoallylic amine 3 in the presence of a catalytic amount of Y