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258851-74-0

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258851-74-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 258851-74-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,5,8,8,5 and 1 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 258851-74:
(8*2)+(7*5)+(6*8)+(5*8)+(4*5)+(3*1)+(2*7)+(1*4)=180
180 % 10 = 0
So 258851-74-0 is a valid CAS Registry Number.

258851-74-0Relevant articles and documents

Ytterbium(III) triflate/TMSCI: Efficient catalyst for imino ene reaction

Yamanaka, Masamichi,Nishida, Atsushi,Nakagawa, Masako

, p. 159 - 161 (2000)

(equation presented) Ytterbium trifluoromethanesulfonate [Yb(OTf)3] catalyzed the imino ene reaction of N-tosyl aldimine with α-methylstyrene to give a homoallylamine in moderate yield. Furthermore, addition of a catalytic amount of chlorotrime

Palladium-Catalyzed Direct Intramolecular C-N Bond Formation: Access to Multisubstituted Dihydropyrroles

Jiang, Bing,Meng, Fei-Fan,Liang, Qiu-Ju,Xu, Yun-He,Loh, Teck-Peng

, p. 914 - 917 (2017/02/26)

A palladium-catalyzed intramolecular amination of alkenes with retention of olefin functionalization was achieved under mild reaction conditions. In the presence of palladium catalyst, the tosyl-protected amine can directly couple with a double bond to provide versatile dihydropyrrole derivatives in moderate to excellent yields.

Imino ene reaction catalyzed by Ytterbium(III) Triflate and TMSCl or TMSOTf

Yamanaka, Masamichi,Nishida, Atsushi,Nakagawa, Masako

, p. 3112 - 3120 (2007/10/03)

A novel combined system of Yb(OTf)3 with TMSCl or TMSOTf catalyzed an imino ene reaction. The reaction of N-tosylbenzaldimine (1) with α-methylstyrene (2) proceeded smoothly to give homoallylic amine 3 in the presence of a catalytic amount of Y

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