25906-67-6

Basic information

• Product Name: 2,5-bis(dimethylthiocarbamoylsulfanyl)terephthalic acid diethyl ester
• Synonyms: 2,5-bis(dimethylthiocarbamoylsulfanyl)terephthalic acid diethyl ester
• CAS NO: 25906-67-6
• Molecular Weight: 428.53
• Mol File: 25906-67-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2,5-bis(dimethylthiocarbamoylsulfanyl)terephthalic acid diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-bis(dimethylthiocarbamoylsulfanyl)terephthalic acid diethyl ester(25906-67-6)
• EPA Substance Registry System: 2,5-bis(dimethylthiocarbamoylsulfanyl)terephthalic acid diethyl ester(25906-67-6)

Safety Data

• Hazardous Substances Data: 25906-67-6(Hazardous Substances Data)

Upstream product

• 610-92-4 2,5-dihydroxy-1,4-benzenedicarboxylic acid 
• 123-31-9 hydroquinone 
• 5870-38-2 diethyl 2,5-(dihydroxy)terephthalate 
• 25906-63-2 2,5-bis(dimethylthiocarbamoyloxy)terephthalic acid diethyl ester 

Downstream Products

• 154822-13-6 2,5-Dimercapto-1,4-phenylendimethanol 
• 25906-72-3 diethyl 2,5-dimercaptoterephthalate 
• 1227-49-2 3,3'-dithiobis-benzoic acid 
• 25906-66-5 2,5-disulfhydrylbenzene-1,4-dicarboxylic acid 

Relevant articles and documents

Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity

Conductive metal–organic frameworks (MOFs) are an emerging class of materials that rely upon crystallographically-defined charge-transport pathways that can be synthetically designed. Such conductive MOFs, including Mn-based MOFs, have not yet found applications in electrocatalysis at least partly due to restrictions in their tunability, as compositional or structural changes may interrupt the purposefully-designed charge-transport pathways. In this work, we provide an original strategy to exchange a portion of the Mn2+ cations in the conductive MOF Mn2DSBDC (where DSBDC = 2,5-dimercaptoterephthalate) for either Ni2+, Cu2+, or Co2+. The bulk and local structures were characterized using powder X-ray diffraction and element-specific X-ray absorption spectroscopy, respectively, to understand the structural effects of cation exchange, supporting that cation exchange does not alter the overall structure of the MOF. Importantly, using time-domain THz spectroscopy, it was discovered that the cation exchange does not alter the conductivity of the MOF. This finding opens the door to functionalization and tunability with respect to the cation composition in Mn2DSBDC, strongly suggesting applications in electrocatalysis.

A mercapto-functionalized MOFs material and its preparation and to absorb and remove the application of heavy metal ions in the water body

The invention relates to a preparation method for a thiol-functionalization MOFs material and application thereof in adsorption and removal of heavy metal ions in water. The thiol-functionalization MOFs (UiO-66-SH) material can effectively adsorb and remo

Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobility

The reaction of MnCl2 with 2,5-disulfhydrylbenzene-1,4- dicarboxylic acid (H4DSBDC), in which the phenol groups in 2,5-dihydroxybenzene-1,4-dicarboxylic acid (H4DOBDC) have been replaced by thiophenol units, led to the isolation of Mn2(DSBDC), a thiolated analogue of the M2(DOBDC) series of metal-organic frameworks (MOFs). The sulfur atoms participate in infinite one-dimensional Mn-S chains, and Mn2(DSBDC) shows a high surface area and high charge mobility similar to that found in some of the most common organic semiconductors. The synthetic approach to Mn2(DSBDC) and its excellent electronic properties provide a blueprint for a potentially rich area of exploration in microporous conductive MOFs with low-dimensional charge transport pathways.