25910-97-8Relevant academic research and scientific papers
Iron(II) chloride-mediated addition of dialkylmagnesium to carbonyl compounds
Sada, Mutsumi,Matsubara, Seijiro
, p. 800 - 801 (2008/12/21)
Addition reactions to carbonyl compounds with a complex reagent, prepared from organomagnesium and iron(II) chloride, were examined. The reagent works as effective nucleophile to an easily enolizable ketone such as β-tetralone; it also added to keto ester chemoselectively. Copyright
Stereoselective Construction of Quaternary Centres at Ambient Temperature by the Highly Stereocontrolled Migration of Groups Containing sp-, sp2-, and sp3-Hybridized Carbon Atoms
Marson, Charles M.,Walker, Andrew J.,Pickering, Jane,Hobson, Adrian D.,Wrigglesworth, Roger,Edge, Simon J.
, p. 5944 - 5951 (2007/10/02)
A very highly diastereoselective semipinacol rearrangement of 2,3-epoxy alcohols mediated by tin(IV) chloride at ambient temperatures is shown to be applicable to a wide variety of migration groups including methyl, tert-butyl, cyclopropyl, vinyl, alkynyl
New Eudesmane Sesquiterpenoids from Eremophila scoparia
Babidge, Peter J.,Massy-Westropp, Ralph A.
, p. 629 - 633 (2007/10/02)
Three new eudesmane sesquiterpenoids have been isolated from Eremophila scoparia.They are (4aR,6S,7S,8aS)-7-hydroxy-6-(1-hydroxy-1-methylethyl)-4,8a-dimethyl-4a,5,6,7,8,8a-hexahydronaphthalen-2(1H)-one, (4aS,6S,7S,8aS)-7-hydroxy-6-(1-hydroxy-1-methylethyl
