259206-65-0Relevant academic research and scientific papers
Water-soluble phosphanes, 11[±]: Syntheses and coordination chemistry of chiral phosphanyl glycerols and their derivatives - X-ray structure of (R)-Ph2P-CH2-CaH-O-B(Ph)-O-CbH2(Ca-Cb
Brauer, David J.,Machnitzki, Peter,Nickel, Thomas,Stelzer, Othmar
, p. 65 - 73 (2000)
Reaction of (R)-(+)-2,3-epoxy-1-propanol with Ph2PH, Ph(Me)PH, or PhPH2 in the superbasic medium KOH/DMSO affords the novel chiral phosphanes 1a-1c. While 1a is obtained enantiomerically pure, 1b and the secondary phosphane 1c are fo
