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High purity Glycidol 98% TOP1 supplier in China
Cas No: 556-52-5
No Data 100 Metric Ton 1-1000 Kilogram/Day Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Glycidol supplier in China
Cas No: 556-52-5
No Data No Data 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Glycidol
Cas No: 556-52-5
No Data 1 Gram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
2,3-Epoxy-1-propanol
Cas No: 556-52-5
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Glycidol
Cas No: 556-52-5
USD $ 5.0-5.0 / Kilogram 1 Kilogram 1000 Kilogram/Month Enke Pharma-tech Co.,Ltd. (Cangzhou, China ) Contact Supplier
manufacturer Glycidol 99% CAS 556-52-5
Cas No: 556-52-5
USD $ 1.0-2.0 / Kilogram 5 Kilogram 50 Metric Ton/Month Henan Sinotech Import&Export Corporation Contact Supplier
Glycidol Manufacturer 556-52-5 For Fungicides And Gels
Cas No: 556-52-5
No Data 10 Gram 10000 Metric Ton/Month Hubei XinRunde Chemical Co., Ltd Contact Supplier
TIANFU CHEM----Glycidol
Cas No: 556-52-5
No Data 1 Kilogram 10 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
Pharmaceutical Grade CAS 556-52-5 with competitive price
Cas No: 556-52-5
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
BLOOM TECH Advanced API/Technology support Oxiran-2-ylmethanol CAS 556-52-5
Cas No: 556-52-5
No Data 1 Gram 3 Metric Ton/Month Shaanxi BLOOM TECH Co.,Ltd Contact Supplier

556-52-5 Usage

General Description

Odorless clear colorless liquid.

Uses

Stabilizer in manufacturing of vinyl polymers; intermediate in synthesis of glycerol, glycidyl ethers, and amines; additive for oil and synthetic hydraulic fluids; epoxy resin diluent.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

Reactivity Profile

Glycidol is sensitive to moisture. Glycidol is also sensitive to light. Glycidol may polymerize if heated above room temperature. Glycidol may darken on storage. Stability studies of Glycidol stored for two week protected from light indicated definite decomposition at 140° F, and strongly indicated instability at 77° F. A solution of Glycidol in water was found to be unstable when stored at room temperature, even after one day in the dark. Glycidol is incompatible with strong oxidizers. Glycidol will undergo explosive decomposition in the presence of strong acids or bases, salts (such as aluminum chloride, iron(III)chloride or tin(IV) chloride) or metals (such as copper and zinc). Glycidol is also incompatible with nitrates. Glycidol will attack some forms of plastics, rubber and coatings.

Fire Hazard

Glycidol is combustible.

Chemical Properties

colourless liquid

Air & Water Reactions

Sensitive to moisture.

Uses

An epoxide building block
InChI:InChI=1/C2H4O.CH4O/c1-2-3-1;1-2/h1-2H2;2H,1H3

556-52-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (G5809)  Glycidol  96% 556-52-5 G5809-2.5KG 7,452.90CNY Detail
Aldrich (G5809)  Glycidol  96% 556-52-5 G5809-500G 1,843.92CNY Detail
Aldrich (G5809)  Glycidol  96% 556-52-5 G5809-100G 549.90CNY Detail
Aldrich (G5809)  Glycidol  96% 556-52-5 G5809-5G 431.73CNY Detail
Sigma-Aldrich (Y0001048)  Levodropropizine impurity C  European Pharmacopoeia (EP) Reference Standard 556-52-5 Y0001048 1,880.19CNY Detail
Sigma-Aldrich (74595)  (±)-Glycidol  analytical standard 556-52-5 74595-100MG 606.06CNY Detail

556-52-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name glycidol

1.2 Other means of identification

Product number -
Other names 2,3-Epoxy-1-propanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:556-52-5 SDS

556-52-5Synthetic route

allyl alcohol
107-18-6

allyl alcohol

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium In chlorobenzene at 80℃; for 5h;100%
With sodium persulfate; water at 20℃; for 12h; Reagent/catalyst;100%
With tetrabutylphosphonium peroxotantalate; dihydrogen peroxide In water at 0℃; for 5.5h; Schlenk technique; chemoselective reaction;100%
3-monochloro-1,2-propanediol
96-24-2

3-monochloro-1,2-propanediol

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at -5 - 15℃; for 6h; Large scale;98.5%
With sodium hydroxide In water at 18 - 36℃; under 18.7519 Torr; Temperature; Pressure; Concentration; Industrial scale;97.92%
With sodium methylate In methanol at 0 - 15℃; under 2100.21 - 2325.23 Torr; for 0.833333h; Pressure; Temperature;93.76%
4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With zinc(II) nitrate; 1-butyl-3-methylimidazolium nitrate at 175℃; under 20.027 Torr; for 2.5h;98.2%
With zinc-lanthanum mixed oxides at 180℃; under 375.038 Torr; Reagent/catalyst;76.22%
With sodium sulfate at 140 - 180℃; for 3h; Green chemistry;33%
methanol
67-56-1

methanol

DMTr-glycidol

DMTr-glycidol

A

oxiranyl-methanol
556-52-5

oxiranyl-methanol

B

bis(4-methoxyphenyl)phenylmethyl methyl ether
125016-87-7

bis(4-methoxyphenyl)phenylmethyl methyl ether

Conditions
ConditionsYield
With lithium tetrafluoroborate In dichloromethane at 20℃; for 0.25h; deprotection;A 92%
B n/a
glycerol
56-81-5

glycerol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

B

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With 30 wt.% KF/γ-Al2O3 at 80℃; for 1.5h; Catalytic behavior; Reagent/catalyst;A 91.3%
B n/a
With fluorinated Mg-Al hydrotalcite derived basic catalyst at 110℃; for 3h; Reagent/catalyst;A 80.5%
B 10.8%
With Mg/Zr/Sr mixed oxide at 90℃; for 1.5h; Catalytic behavior; Temperature; Concentration; Reagent/catalyst;A 56%
B 40%
2-fluoroethanol
371-62-0

2-fluoroethanol

2-fluoro-2-phenylethanol
2932-58-3

2-fluoro-2-phenylethanol

A

trans-3-chloroallyl 2,3-epoxypropyl ether
108788-73-4

trans-3-chloroallyl 2,3-epoxypropyl ether

B

2-(2-Fluoro-2-phenyl-ethoxymethyl)-oxirane
128367-32-8

2-(2-Fluoro-2-phenyl-ethoxymethyl)-oxirane

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate at 25℃; for 24h; Yields of byproduct given;A n/a
B 75%
C n/a
2-fluoroethanol
371-62-0

2-fluoroethanol

trans-2-fluorocyclohexanol
14365-32-3

trans-2-fluorocyclohexanol

2-((1S,2S)-2-Fluoro-cyclohexyloxymethyl)-oxirane
128920-99-0

2-((1S,2S)-2-Fluoro-cyclohexyloxymethyl)-oxirane

B

trans-3-chloroallyl 2,3-epoxypropyl ether
108788-73-4

trans-3-chloroallyl 2,3-epoxypropyl ether

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate at 25℃; for 24h; Yields of byproduct given;A 65%
B n/a
C n/a
4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

A

2,5-Bis(hydroxymethyl)-1,4-dioxane
14236-12-5

2,5-Bis(hydroxymethyl)-1,4-dioxane

B

2,6-bis(hydroxymethyl)-1,4-dioxane

2,6-bis(hydroxymethyl)-1,4-dioxane

C

3-(oxrian-2-yloxy)propane-1,2-diol
1416557-67-9

3-(oxrian-2-yloxy)propane-1,2-diol

D

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With sodium chloride at 175℃; under 20.027 Torr; for 0.75h;A n/a
B n/a
C n/a
D 62%
glycerol
56-81-5

glycerol

A

1,3-dioxolane-4-methanol
5464-28-8

1,3-dioxolane-4-methanol

B

glycerol formal
4740-78-7

glycerol formal

C

glycolic Acid
79-14-1

glycolic Acid

D

ethyl 2-hydroxyacetate
623-50-7

ethyl 2-hydroxyacetate

E

diglycerol
627-82-7

diglycerol

F

oxiranyl-methanol
556-52-5

oxiranyl-methanol

G

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

H

acrolein
107-02-8

acrolein

Conditions
ConditionsYield
With pretreated aluminium vanadium phosphate In water at 280℃; under 760.051 Torr; Catalytic behavior; Activation energy; Reagent/catalyst; Temperature;A n/a
B n/a
C n/a
D n/a
E n/a
F n/a
G n/a
H 62%
glycerol
56-81-5

glycerol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

B

methyl ((2-oxo-1,3-dioxolan-4-yl)methyl)carbonate
76913-29-6

methyl ((2-oxo-1,3-dioxolan-4-yl)methyl)carbonate

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With potassium fluoride at 80℃; for 1.5h; Catalytic behavior; Reagent/catalyst;A 58.4%
B n/a
C n/a
With tetrabutylammomium bromide at 160℃; under 8250.83 Torr; for 0.05h; Flow reactor;
ethanol
64-17-5

ethanol

4-chloromethyl-1,3,2-dioxathiolane 2-oxide
55685-62-6, 55685-63-7, 146864-18-8, 146864-19-9, 15121-11-6

4-chloromethyl-1,3,2-dioxathiolane 2-oxide

phenol
108-95-2

phenol

A

diethyl sulphite
623-81-4

diethyl sulphite

B

1-phenoxy-2,3-propanediol
538-43-2

1-phenoxy-2,3-propanediol

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With sodium In toluene for 1h; Heating;A 20%
B 45%
C n/a
dihydrogen peroxide
7722-84-1

dihydrogen peroxide

allyl alcohol
107-18-6

allyl alcohol

A

water
7732-18-5

water

B

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With titanium-containing zeolite In methanol at 35℃; Mechanism; Solvent;A n/a
B 29.3%
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

glycerol
56-81-5

glycerol

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
at 150℃; under 35 Torr; Erhitzen des Reaktionsprodukts unter 10-15 Torr bis auf 240grad;
at 240℃; under 10 - 15 Torr;
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

glycerol
56-81-5

glycerol

A

oxiranyl-methanol
556-52-5

oxiranyl-methanol

B

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
at 240℃; unter vermindertem Druck;
3-iodo-propane-1,2-diol
554-10-9

3-iodo-propane-1,2-diol

silver(1+) stearate
3507-99-1

silver(1+) stearate

A

oxiranyl-methanol
556-52-5

oxiranyl-methanol

B

stearic acid
57-11-4

stearic acid

Conditions
ConditionsYield
verreibt man geschmolzenes Glycerin-α-jodhydrin;
at 100℃; under 5 Torr; 3/4 Stdn. Erhitzen;
at 100℃; under 5 Torr; beim Verreiben oder 3/4 stdg.Erhitzen;
3-iodo-propane-1,2-diol
554-10-9

3-iodo-propane-1,2-diol

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With silver(1+) stearate at 100℃; under 5 Torr;
sodium ethanolate
141-52-6

sodium ethanolate

3-monochloro-1,2-propanediol
96-24-2

3-monochloro-1,2-propanediol

oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-monochloro-1,2-propanediol
96-24-2

3-monochloro-1,2-propanediol

glycerol
56-81-5

glycerol

A

diglycerol
627-82-7

diglycerol

B

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
die Mononatriumverbindung reagiert;
glycerol
56-81-5

glycerol

A

3-Hydroxypropanal
2134-29-4

3-Hydroxypropanal

B

diglycerol
627-82-7

diglycerol

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

D

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

Conditions
ConditionsYield
at 170 - 250℃; Produkt 5: Acrylaldehyd;
epichlorohydrin
106-89-8

epichlorohydrin

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With potassium acetate Behandeln des entstandenen Glycidacetats in aether. Loesung mit gepulvertem Aetznatron;
With potassium acetate at 150℃; Behandeln des entstandenen Glycidacetats in aether. Loesung mit gepulvertem Aetznatron;
Glycidaldehyde
765-34-4

Glycidaldehyde

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With water; aluminum tri-tert-butoxide 1.) benzene, 20 deg C, 8 h, 2.) benzene; Yield given. Multistep reaction;
triallyl orthoformate
16754-50-0

triallyl orthoformate

A

2,3-epoxypropyl formate
73376-04-2

2,3-epoxypropyl formate

B

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With 1-propenylbenzene; dihydrogen peroxide In tetrahydrofuran Product distribution; Ambient temperature; competition experiments for intra- vs. intermolecular epoxidation;
(+/-)-2,3-dihydroxypropyl tosylate
51704-66-6

(+/-)-2,3-dihydroxypropyl tosylate

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
Mechanism;
ethanol
64-17-5

ethanol

allyl alcohol
107-18-6

allyl alcohol

A

3-ethoxy-1,2-propanediol
1874-62-0

3-ethoxy-1,2-propanediol

B

2-ethoxy-propane-1,3-diol
22598-16-9

2-ethoxy-propane-1,3-diol

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

D

glycerol
56-81-5

glycerol

Conditions
ConditionsYield
With titanium silicate; dihydrogen peroxide In ethanol at 65℃; for 24h; Product distribution; var. temp., var. time, var. solvent, var. acidity of TS-1;
butanoic acid ethyl ester
105-54-4

butanoic acid ethyl ester

allyl alcohol
107-18-6

allyl alcohol

A

(+/-)-glycidyl butyrate
2461-40-7

(+/-)-glycidyl butyrate

B

allyl butyrate
2051-78-7

allyl butyrate

C

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Conditions
ConditionsYield
With Novozym 435; dihydrogen peroxide 1.) 15 min, 2.) 40 deg C, 16 h; Yield given. Multistep reaction. Yields of byproduct given;
oxiranyl-methanol
556-52-5

oxiranyl-methanol

benzoyl chloride
98-88-4

benzoyl chloride

Conditions
ConditionsYield
With pyridine In dichloromethane at 0℃; for 1h;100%
With pyridine; dmap In dichloromethane94%
With dmap In dichloromethane at 20℃; for 24h;90%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

N-methylaniline
100-61-8

N-methylaniline

3-(methyl(phenyl)amino)propane-1,2-diol
42871-95-4

3-(methyl(phenyl)amino)propane-1,2-diol

Conditions
ConditionsYield
In methanol for 48h; Reflux;100%
In ethanol at 120℃; for 0.333333h; Microwave irradiation;81%
triethylsilyl chloride
994-30-9

triethylsilyl chloride

oxiranyl-methanol
556-52-5

oxiranyl-methanol

triethyl(oxiran-2-ylmethoxy)silane
17865-33-7

triethyl(oxiran-2-ylmethoxy)silane

Conditions
ConditionsYield
With 1H-imidazole; triethylamine In N,N-dimethyl-formamide silylation;100%
With 1H-imidazole; dmap In dichloromethane at 20℃; for 1h; Inert atmosphere;100%
With 1H-imidazole; dmap In dichloromethane at 0 - 20℃; for 3h;95%
With dmap; triethylamine In dichloromethane at 0 - 20℃;84%
With pyridine In diethyl ether for 0.75h;
carbon dioxide
124-38-9

carbon dioxide

oxiranyl-methanol
556-52-5

oxiranyl-methanol

4-hydroxymethyl-1,3-dioxolan-2-one
931-40-8

4-hydroxymethyl-1,3-dioxolan-2-one

Conditions
ConditionsYield
With C25H13O12Si(5-)*3Ni(2+)*HO(1-); tetrabutylammomium bromide In neat (no solvent) at 99.84℃; under 7500.75 Torr; for 3h; Catalytic behavior; Autoclave;100%
With tetrabutylammomium bromide In neat (no solvent) at 60℃; under 7500.75 Torr; for 3h; Catalytic behavior; Reagent/catalyst; Temperature; Autoclave; Green chemistry;99%
With Cu7(H1L)2(TPT)3(H2O)6; tetrabutylammomium bromide at 100℃; under 760.051 Torr; for 3h; Catalytic behavior; Kinetics; Autoclave;99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

benzyl bromide
100-39-0

benzyl bromide

Benzyloxymethyl-oxiran
2930-05-4

Benzyloxymethyl-oxiran

Conditions
ConditionsYield
Stage #1: oxiranyl-methanol With sodium hydride In tetrahydrofuran at 0℃;
Stage #2: benzyl bromide In tetrahydrofuran for 7h;
100%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃;98%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃;98%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-(2,3-dihydroxypropyl)-5,5-dimethylhydantoin
55954-09-1

3-(2,3-dihydroxypropyl)-5,5-dimethylhydantoin

1,3-bis(2,3-dihydroxypropyl)-5,5-dimethylhydantoin

1,3-bis(2,3-dihydroxypropyl)-5,5-dimethylhydantoin

Conditions
ConditionsYield
With lithium chloride In isopropyl alcohol at 80℃; for 3h;100%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-(2-hydroxypropyl)-5,5-dimethylhydantoin
29071-93-0

3-(2-hydroxypropyl)-5,5-dimethylhydantoin

3-(2-hydroxyethyl)-1-(2,3-dihydroxypropyl)-5,5-dimethylhydantoin

3-(2-hydroxyethyl)-1-(2,3-dihydroxypropyl)-5,5-dimethylhydantoin

Conditions
ConditionsYield
With lithium chloride In isopropyl alcohol at 80℃; for 3h;100%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

tert-butylchlorodiphenylsilane
58479-61-1

tert-butylchlorodiphenylsilane

tert-butyl(oxiran-2-ylmethoxy)diphenylsilane
194805-72-6

tert-butyl(oxiran-2-ylmethoxy)diphenylsilane

Conditions
ConditionsYield
With 1H-imidazole In dichloromethane at 0 - 21℃; for 17h; Schlenk technique;100%
With 1H-imidazole In chloroform for 1h; Ambient temperature;97%
With 1H-imidazole In dichloromethane at 20℃;90%
N-(2-iodophenyl)benzenesulfonamide
54189-90-1

N-(2-iodophenyl)benzenesulfonamide

oxiranyl-methanol
556-52-5

oxiranyl-methanol

N-(2-Iodo-phenyl)-N-oxiranylmethyl-benzenesulfonamide
181281-13-0

N-(2-Iodo-phenyl)-N-oxiranylmethyl-benzenesulfonamide

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 20℃; Inert atmosphere;100%
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran for 1h; Ambient temperature;80%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-nitrobenzenesulphonyl chloride
121-51-7

3-nitrobenzenesulphonyl chloride

glycidyl nosylate
152333-94-3

glycidyl nosylate

Conditions
ConditionsYield
With triethylamine In toluene at -20 - -10℃; for 20h; Inert atmosphere;100%
With triethylamine In dichloromethane at 4℃; for 5.5h;51%
With triethylamine In dichloromethane at 0℃; for 1.25h;5 g
Stage #1: oxiranyl-methanol With triethylamine In dichloromethane at 0℃; for 0.25h;
Stage #2: 3-nitrobenzenesulphonyl chloride In dichloromethane at 0℃; for 1h;
5 g
3-aminopropyltriethoxysilane
919-30-2

3-aminopropyltriethoxysilane

oxiranyl-methanol
556-52-5

oxiranyl-methanol

Gly-APTES

Gly-APTES

Conditions
ConditionsYield
at 0 - 50℃; for 1h;100%
C149H300N32O40

C149H300N32O40

oxiranyl-methanol
556-52-5

oxiranyl-methanol

C185H372N32O64

C185H372N32O64

Conditions
ConditionsYield
With potassium carbonate In water for 72h;100%
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

2-oxiranylmethylisoindole-1,3-dione
5455-98-1

2-oxiranylmethylisoindole-1,3-dione

oxiranyl-methanol
556-52-5

oxiranyl-methanol

C72H107N3O34

C72H107N3O34

Conditions
ConditionsYield
Stage #1: 1,1,1-tri(hydroxymethyl)propane With potassium tert-butylate In tetrahydrofuran at 120℃; for 18h; Inert atmosphere;
Stage #2: oxiranyl-methanol In tetrahydrofuran at 120℃; for 0.5h; Inert atmosphere;
Stage #3: 2-oxiranylmethylisoindole-1,3-dione In tetrahydrofuran at 120℃; Inert atmosphere;
100%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

acetone
67-64-1

acetone

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

Conditions
ConditionsYield
erbium(III) triflate at 20℃; for 48h;99%
ruthenium trichloride for 2h; Cycloaddition; Heating;89%
iron(III) trifluoroacetate for 4h; acetonide formation; Heating;89%
With boron fluoride ether
(Z)-9-octadecenoyl chloride
112-77-6

(Z)-9-octadecenoyl chloride

oxiranyl-methanol
556-52-5

oxiranyl-methanol

(Z)-(oxiran-2-yl)methyl octadec-9-enoate
5431-33-4

(Z)-(oxiran-2-yl)methyl octadec-9-enoate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; Inert atmosphere;99%
With triethylamine In acetonitrile at 0 - 20℃; for 12.5h; Inert atmosphere;91%
With dmap In dichloromethane at 20℃; for 4h;86%
With triethylamine In diethyl ether for 12h; Ambient temperature;1.00 g
4-(2-hydroxyethylamino)-2-methyl-6,7-dihydropyrimido<5,4-b><1,4>oxazin-7(8H)-one
110858-76-9

4-(2-hydroxyethylamino)-2-methyl-6,7-dihydropyrimido<5,4-b><1,4>oxazin-7(8H)-one

oxiranyl-methanol
556-52-5

oxiranyl-methanol

8-(2,3-Dihydroxy-propyl)-4-(2-hydroxy-ethylamino)-2-methyl-8H-pyrimido[5,4-b][1,4]oxazin-7-one
110858-93-0

8-(2,3-Dihydroxy-propyl)-4-(2-hydroxy-ethylamino)-2-methyl-8H-pyrimido[5,4-b][1,4]oxazin-7-one

Conditions
ConditionsYield
With tetrabutylammomium bromide In benzene99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

N-ethylbenzylamine
14321-27-8

N-ethylbenzylamine

3-[benzyl(ethyl)amino]propane-1,2-diol

3-[benzyl(ethyl)amino]propane-1,2-diol

Conditions
ConditionsYield
In ethanol at 140℃; under 2585.81 Torr; for 0.0666667h; microwave irradiation;99%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-(3,4-dihydroisoquinolin-2(1H)-yl)propane-1,2-diol
63431-46-9

3-(3,4-dihydroisoquinolin-2(1H)-yl)propane-1,2-diol

Conditions
ConditionsYield
In ethanol at 140℃; under 2585.81 Torr; for 0.0666667h; microwave irradiation;99%
1-(2-Methoxyphenyl)piperazine
35386-24-4

1-(2-Methoxyphenyl)piperazine

oxiranyl-methanol
556-52-5

oxiranyl-methanol

3-<4-(2-Methoxyphenyl)piperazinyl>-1,2-propandiol
117067-06-8

3-<4-(2-Methoxyphenyl)piperazinyl>-1,2-propandiol

Conditions
ConditionsYield
In ethanol at 140℃; under 2585.81 Torr; for 0.0666667h; microwave irradiation;99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

trimethyl gallium
1445-79-0

trimethyl gallium

((CH3)2GaOCH2C2H3O)2

((CH3)2GaOCH2C2H3O)2

Conditions
ConditionsYield
In dichloromethane react. GaMe3 with 1 equiv. rac-2,3-epoxy-1-propanol (CH2Cl2, -78°C);99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

(2R,2‘R)-di-tert-butyl 3,3‘-disulfanediylbis(2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)propanoate)
139592-37-3

(2R,2‘R)-di-tert-butyl 3,3‘-disulfanediylbis(2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)propanoate)

N-fluorenylmethoxycarbonyl-S-[2,3-dihydroxy-(2RS)-propyl]-(R)-cysteine tert-butyl ester

N-fluorenylmethoxycarbonyl-S-[2,3-dihydroxy-(2RS)-propyl]-(R)-cysteine tert-butyl ester

Conditions
ConditionsYield
Stage #1: (2R,2‘R)-di-tert-butyl 3,3‘-disulfanediylbis(2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)propanoate) With hydrogenchloride; sulfuric acid; zinc In methanol; dichloromethane; water at 20℃; for 0.25h; Inert atmosphere;
Stage #2: oxiranyl-methanol In methanol; dichloromethane; water at 40℃; for 5h; Inert atmosphere;
99%
Stage #1: (2R,2‘R)-di-tert-butyl 3,3‘-disulfanediylbis(2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)propanoate) With hydrogenchloride; sulfuric acid; zinc In methanol; dichloromethane at 0℃; for 0.5h;
Stage #2: oxiranyl-methanol In methanol; dichloromethane at 40℃; for 3h;
84%
phenylphosphonate
1571-33-1

phenylphosphonate

oxiranyl-methanol
556-52-5

oxiranyl-methanol

C12H19O7P

C12H19O7P

Conditions
ConditionsYield
In acetone at 50℃; for 6.5h;99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

(2,3-dihydrothieno[3,4-b][1,4]dioxin-3-yl)methanol
146796-02-3

(2,3-dihydrothieno[3,4-b][1,4]dioxin-3-yl)methanol

C10H14O5S

C10H14O5S

Conditions
ConditionsYield
With 2-methylimidazole at 25 - 40℃; for 168h; Sealed tube;99%
oxiranyl-methanol
556-52-5

oxiranyl-methanol

methylamine
74-89-5

methylamine

3-methylamino-propane-1,2-diol
40137-22-2

3-methylamino-propane-1,2-diol

Conditions
ConditionsYield
at 55℃; under 225.023 - 31503.2 Torr; for 0.666667h; Pressure; Autoclave; Green chemistry;98.99%
In water at 30℃; for 4 - 5h;92.7%
unter Kuehlung;
oxiranyl-methanol
556-52-5

oxiranyl-methanol

glycerol
56-81-5

glycerol

Conditions
ConditionsYield
With water at 60℃; for 4h;98%
With water at 70℃; Rate constant; variation of pH;
With sulfuric acid; water
oxiranyl-methanol
556-52-5

oxiranyl-methanol

benzyl isothiocyanate
3173-56-6

benzyl isothiocyanate

benzylcarbamic acid oxiranylmethyl ester
170956-42-0

benzylcarbamic acid oxiranylmethyl ester

Conditions
ConditionsYield
In dichloromethane at 25℃; for 24h;98%
With sodium carbonate In toluene for 2h; Heating;76%
With 1,3-dichlorotetrabutyldistannoxane In dichloromethane62%
With 1,3-dichlorotetrabutyldistannoxane In dichloromethane at 20℃; for 48h;62%

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