25936-85-0Relevant academic research and scientific papers
Towards γ-Rubromycin: Model Studies, Development of a C3Building Block, and Synthesis of 4′-Silyl-γ-rubromycin
Wilsdorf, Michael,Reissig, Hans-Ulrich
supporting information, p. 5747 - 5756 (2016/12/14)
The human telomerase inhibitor γ-rubromycin belongs to a class of natural products, which features a rare [5,6]-bisbenzannulated spiroketal core as its central structural motif. Also termed “aromatic spiroketals”, these scaffolds pose great challenges to
The synthesis of the pyranonaphthoquinones dehydroherbarin and anhydrofusarubin using Wacker oxidation methodology as a key step and other unexpected oxidation reactions with ceric ammonium nitrate and salcomine
Pillay, Adushan,Rousseau, Amanda L.,Fernandes, Manuel A.,De Koning, Charles B.
, p. 7809 - 7819 (2013/04/23)
The synthesis of two closely related pyranonaphthoquinones, dehydroherbarin and anhydrofusarubin, is described. The construction of the naphthalene nuclei was achieved using the Stobbe condensation reaction using 2,4- dimethoxybenzaldehyde and 2,4,5-trime
A concise synthesis of the naphthalene portion of purpuromycin
Lowell, Andrew N.,Fennie, Michael W.,Kozlowski, Marisa C.
, p. 1911 - 1918 (2008/09/18)
(Chemical Equation Presented) A concise synthesis of naphthalene compounds for incorporation into a synthetic sequence for the rubromycin family of natural products is presented. These highly substituted naphthalenes are generated in seven and nine steps,
Base- and light-assisted synthesis of anthracenes from 3-allylnaphthalene- 2-carbaldehydes
De Koning, Charles B.,Manzini, Sunnyboy S.,Michael, Joseph P.,Mmutlane, Edwin M.,Tshabidi, Tefo R.,Van Otterlo, Willem A.L.
, p. 555 - 564 (2007/10/03)
The synthesis of substituted anthracenes from naphthalene precursors is described. The key step involved heating ortho-allyl substituted naphthalene-2-carbaldehydes and potassium t-butoxide in DMF with concomitant irradiation from a high pressure mercury
Ethyl(or methyl) 4-acetoxy(or propionyloxy)-5,6,7 or 8-di(or tri-)substituted-2-naphthoates
-
, (2008/06/13)
Novel antiviral ring-substituted ethyl or methyl 4-acetoxy (or propionyloxy)-2-naphthoates are provided.
