834866-83-0Relevant academic research and scientific papers
Towards γ-Rubromycin: Model Studies, Development of a C3Building Block, and Synthesis of 4′-Silyl-γ-rubromycin
Wilsdorf, Michael,Reissig, Hans-Ulrich
supporting information, p. 5747 - 5756 (2016/12/14)
The human telomerase inhibitor γ-rubromycin belongs to a class of natural products, which features a rare [5,6]-bisbenzannulated spiroketal core as its central structural motif. Also termed “aromatic spiroketals”, these scaffolds pose great challenges to
A concise synthesis of the naphthalene portion of purpuromycin
Lowell, Andrew N.,Fennie, Michael W.,Kozlowski, Marisa C.
, p. 1911 - 1918 (2008/09/18)
(Chemical Equation Presented) A concise synthesis of naphthalene compounds for incorporation into a synthetic sequence for the rubromycin family of natural products is presented. These highly substituted naphthalenes are generated in seven and nine steps,
Base- and light-assisted synthesis of anthracenes from 3-allylnaphthalene- 2-carbaldehydes
De Koning, Charles B.,Manzini, Sunnyboy S.,Michael, Joseph P.,Mmutlane, Edwin M.,Tshabidi, Tefo R.,Van Otterlo, Willem A.L.
, p. 555 - 564 (2007/10/03)
The synthesis of substituted anthracenes from naphthalene precursors is described. The key step involved heating ortho-allyl substituted naphthalene-2-carbaldehydes and potassium t-butoxide in DMF with concomitant irradiation from a high pressure mercury
