259856-85-4

Basic information

• Product Name: (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane
• Synonyms: (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane
• CAS NO: 259856-85-4
• Molecular Weight: 252.401
• Mol File: 259856-85-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane(259856-85-4)
• EPA Substance Registry System: (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane(259856-85-4)

Safety Data

• Hazardous Substances Data: 259856-85-4(Hazardous Substances Data)

Upstream product

• 259856-84-3 (2R)-1-(tert-butyldimethylsilyloxy)-4-(1,3-dithian-2-yl)-4-phenyl-2-butanol 
• 5425-44-5 2-Phenyl-[1,3]dithiane 

Downstream Products

• 1026470-49-4 Trifluoro-acetic acid (2S,4R)-2-phenyl-1-(2,2,2-trifluoro-acetyl)-piperidin-4-yl ester 
• 259856-87-6 (2S,4R)-(-)-4-Acetoxy-2-phenyl-1-trifluoroacetylpiperidine 
• 259856-82-1 (3R)-3-hydroxy-5-oxo-5-phenylpentanenitrile 
• 259856-83-2 (2S,4R)-(-)-2-Phenylpiperidine-4-ol 
• 259856-86-5 (3R)-5-(1,3-dithian-2-yl)-3-hydroxy-5-phenylpentanenitrile 

Relevant articles and documents

A new route to (2S,4R)- and (2R,4S)-4-hydroxypipecolic acid

Both enantiomers of cis-4-hydroxypipecolic acid have been prepared by asymmetric synthesis using (S)- or (R)-glycidol as the chiral source, and involving a stereoselective hydrogenation of a six-membered cyclic imine. The latter is obtained by reduction and cyclization of a cyano β-hydroxy ketone.