25994-02-9

Upstream product

• 544-16-1 n-Butyl nitrite 
• 495-40-9 propiophenone 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 

Downstream Products

• 5897-76-7 (+/-)-(1R,2S)-2-amino-1-phenyl-1-butanol 
• 6170-27-0 (+/-)-(1R,2S)-2-amino-1-phenyl-1-butanol hydrochloride 
• 65737-01-1 erythro-2-benzamido-1-phenylbutan-1-ol 
• 863012-33-3 4-ethyl-2-(4-iodo-2-methoxy-pyridin-3-yl)-5-phenyl-imidazol-1-ol 

Relevant academic research and scientific papers

Dual photoredox/palladium-catalyzed C-H acylation of 2-arylpyridines with oxime esters

An unprecedented dual photoredox/palladium-catalyzed iminyl-radical-mediated C-C bond cleavage and directed ortho C-H acylation of 2-arylpyridines by using oxime esters is described. Oxime esters can serve as efficient acyl sources through formation of the corresponding acyl radicals by photoredox-catalyzed iminyl-radical-mediated C-C bond cleavage. This redox-neutral protocol features excellent regioselectivity, a broad substrate scope, and good functional-group tolerance with respect to both components, giving a broad range of aryl ketones with generally good yields.

Imidazole based kinase inhibitors

The present invention provides compounds having Formula I and their use for the treatment of cancer.

Extraction and spectrophotometric determination of palladium(H) with 1-phenyl-1,2-butanedione dioxime

Extraction and spectrophotometric determination of palladium(II) has been carried out using a new reagent 1-phenyl-1,2-butanedione dioxime (H2PBDD) which forms a yellow coloured complex with Pd(II). The complex can be quantitatively extracted i

A Novel and Efficient Method for the Preparation of α-Hydroxyimino Carbonyl Compounds from α,β-Unsaturated Carbonyl Compounds with Butyl Nitrite and Phenylsilane Catalyzed by a Cobalt(II) Complex

Various α,β-unsaturated carbonyl compounds, such as α,β-unsaturated esters, α,β-unsaturated ketones, α,β-unsaturated nitriles, and α,β-unsaturated amides, were directly converted to the corresponding α-hydroxyimino carbonyl compounds in high yields on treatment with butyl nitrite and phenylsilane in the presence of a catalytic amount of N,N'-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II) complex under mild conditions.