26040-74-4

Upstream product

• 67-56-1 methanol 
• 111-71-7 heptanal 

Downstream Products

• 1338533-34-8 methyl 2-(2-formyl-4-acetamidophenoxy)hexanoate 
• 526196-92-9 (2-n-butyl-benzofuran-5-yl)-acetamide 
• 1338533-35-9 2-(2-formyl-4-acetamidophenoxy)hexanoic acid 
• 1278585-69-5 N-(2-butyl-3-(4-(3-(dibutylamino)propoxy)benzoyl)benzofuran-5-yl)acetamide 
• 1278585-66-2 2-n-butyl-3-(4-hydroxybenzoyl)-5-acetamidobenzofuran 
• 1278585-63-9 2-n-butyl-3-(4-methoxybenzoyl)-5-acetamidobenzofuran 
• 18281-48-6 2-[(2,4-Dinitro-phenyl)-hydrazono]-heptanoic acid methyl ester 
• 54004-30-7 (E)-methyl hept-3-enoate 
• 3507-62-8 monoamyl succinic acid 

Relevant academic research and scientific papers

One-pot oxidative bromination – Esterification of aldehydes to 2-bromoesters using cerium (IV) ammonium nitrate and lithium bromide

A two-step, one-pot reaction of aldehydes with the CAN/LiBr oxidation system under solvent-free conditions followed by the addition of methanol affords methyl α-bromocarboxylates. The oxidation of aldehydes with methanol using this system gives only methyl esters. A facile method, which does not require special equipment, was developed for the synthesis of 2-bromoesters from aliphatic aldehydes with carbon chain lengths of 5–10 atoms.