260784-04-1

Basic information

• Product Name: benzyl (2R,2'S)-1-(2'-acetamido-4'-methylpentanoyl)aziridine-2-carboxylate
• Synonyms: benzyl (2R,2'S)-1-(2'-acetamido-4'-methylpentanoyl)aziridine-2-carboxylate
• CAS NO: 260784-04-1
• Molecular Weight: 332.4
• Mol File: 260784-04-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl (2R,2'S)-1-(2'-acetamido-4'-methylpentanoyl)aziridine-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (2R,2'S)-1-(2'-acetamido-4'-methylpentanoyl)aziridine-2-carboxylate(260784-04-1)
• EPA Substance Registry System: benzyl (2R,2'S)-1-(2'-acetamido-4'-methylpentanoyl)aziridine-2-carboxylate(260784-04-1)

Safety Data

• Hazardous Substances Data: 260784-04-1(Hazardous Substances Data)

Upstream product

• 1188-21-2 N-Ac-Leu 
• 86123-05-9 benzyl (R)-aziridine-2-carboxylate 

Relevant articles and documents

Dipeptides containing D-serine or D-isoserine from the same (R)-aziridine-2-imide by a simple reversal of the synthetic procedure

The ring expansion of 3-unsubstituted (R)-aziridine-2-imide- containing dipeptide under acidic conditions gives rise to oxazoline-5-imide regio and stereoselectively, which can be hydrolysed to the dipeptide containing D-isoserine. On the other hand, the ring opening of 3-unsubstituted (R)-aziridine-2-ester dipeptide, easily obtained from the same (R)-aziridine, gives the regioisomeric dipeptide containing D-serine.