26087-01-4

Upstream product

• 614-47-1 1,3-diphenyl-propen-3-one 
• 26086-60-2 2-azido-4'-chloroacetophenone 
• 100-52-7 benzaldehyde 
• 94-41-7 benzalacetophenone 
• 611-91-6 2,3-dibromo-1,3-diphenylpropane-1-one 
• 1816-88-2 2-azido-1-phenylethan-1-one 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 1361316-77-9 1,3-diphenyl-2-((triphenylphosphoranylidene)amino)prop-2-en-1-one 
• 1361316-63-3 [2-(4-methylphenyl)-5-phenyloxazol-4-yl](phenyl)methanol 
• 1361316-64-4 [2-(2-chlorophenyl)-5-phenyloxazol-4-yl](phenyl)methanol 
• 1361316-66-6 [2-(3-chlorophenyl)-5-phenyloxazol-4-yl](phenyl)methanol 
• 1361316-74-6 (2-methyl-5-phenyloxazol-4-yl)(phenyl)methanol 
• 1361316-61-1 [2-(4-chlorophenyl)-5-phenyloxazol-4-yl](phenyl)methanol 
• 1361316-62-2 [2-(4-fluorophenyl)-5-phenyloxazol-4-yl](phenyl)methanol 
• 24806-70-0 N-[(Z)-1-oxo-1,3-diphenylprop-2-en-2-yl]benzamide 
• 133229-66-0 (2,5-diphenyloxazol-4-yl)(phenyl)methanol 
• 1427302-12-2 1-(4-benzoyl-2-methyl-5-phenyl-1H-pyrrol-3-yl)ethanone 
• 56445-51-3 (4,5-diphenyl-1H-pyrazol-3-yl)(phenyl)methanone 
• 1544451-85-5 5-benzoyl-4-phenyl-1H-imidazole-2-amine 
• 1022-86-2 2-benzoylindole 

Relevant academic research and scientific papers

A Bu4N[Fe(CO)3(NO)]-Catalyzed Hemetsberger–Knittel Indole Synthesis

The nucleophilic Fe complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of aryl vinyl azides to give the corresponding indole derivatives in good to excellent yields.

A new synthetic strategy towards 2,4,5-trisubstituted 1H-imidazoles and highly substituted pyrrolo[1,2-c]imidazoles by use of α-azidochalcones via Michael addition-cyclization followed by Wittig reaction

Efficient and facile protocols for the preparation of highly functionalized 1H-imidazoles and 5H-pyrrolo[1,2-c]imidazoles are described. Heating a mixture of an α-azidochalcones and N,N,N′,N′-tetramethyl guanidine under neat conditions gave the corresponding 2,4,5-trisubstituted 1H-imidazole via Michael addition-cyclization in excellent yields. Subsequently, the prepared 1H-imidazoles undergo addition-Wittig reaction with acetylenic esters in presence of triphenylphosphine in dichloromethane to afford 5H-pyrrolo[1,2-c]imidazoles in high yields.

Visible-Light-Mediated Synthesis of Pyrazines from Vinyl Azides Utilizing a Photocascade Process

A convenient method for the synthesis of substituted pyrazines from vinyl azides has been developed. This method is enabled by a dual-energy and electron-transfer strategy by visible-light photocatalysis. Initially, vinyl azides are activated by a triplet sensitization process from an excited ruthenium photocatalyst in the presence of water to form dihydropyrazines, followed by a single-electron-transfer (SET) process under oxygen (air) atmosphere that leads to the tetrasubstituted pyrazines in good to excellent yields.

A multi-substituted 4 - hydroxy pyrazole derivatives of the preparation method

The invention provides a preparation method of a multi-substituted 4-hydroxypyrazole derivative. An alkenyl azide derivative and a hydrazine compound which are chemically synthesized easily are generated under the condition of room temperature. The provid

One-pot three-component approach to the synthesis of polyfunctional pyrazoles

A simple, multicomponent, and straightforward reaction of vinyl azide, aldehyde, and tosylhydrazine affords the construction of 3,4,5-trisubstituted 1H-pyrazoles regioselectively in the presence of base with moderate to excellent yields. A range of functionality could be tolerated in this methodology, and a possible mechanism is proposed.

Indium trichloride catalyzed regioselective synthesis of substituted pyrroles in water

A facile and regioselective synthesis of polysubstituted pyrroles from α-azido chalcones and 1,3-dicarbonyl compounds is described. Indium trichloride in water is found to be efficient in catalyzing this transformation.

Unexpected synthesis of 2,4,5-trisubstituted oxazoles via a tandem aza-wittig/michael/isomerization reaction of vinyliminophosphorane

2,4,5-Trisubstituted oxazoles 6 were unexpectedly prepared from a tandem reaction of vinyliminophosphorane 3 with various acyl chlorides in a one-pot fashion.

Temperature-dependent regioselective synthesis of 1,2,4-triazino[2,3-b] indazoles and 3H-1,4-benzodiazepines by domino-Staudinger/aza-Wittig/ isomerization reaction

o-Azidobenzaldimine 8 reacted with triphenylphosphane at 0 °C with warming to room temperature to give 1,2,4-triazino[2,3-b]indazoles 12 by a domino-Staudinger/aza-Wittig/isomerization reaction. However, when heated to 80 °C the same reaction mixture affo

A novel synthesis of α-azidocinnamates, α-azido-α,β-unsaturated ketones and β-azidostyrenes mediated by cerium(IV) ammonium nitrate

Cerium(IV) ammonium nitrate mediated addition of azide to cinnamic esters, acids and α,β-unsaturated ketones, followed by reaction with sodium acetate afforded the α-azidocinnamates, β-azidostyrenes and α-azido-α,β- unsaturated ketones, respectively, in good yields. (C) 2000 Elsevier Science Ltd.

A VERSATILE SYNTHESIS OF VICINAL DIAZIDES USING HYPERVALENT IODINE

A convenient synthesis of vicinal diazides from olefins using C6H5IO/HOAc/NaN3 is described.A mechanism is proposed which accounts for the stereochemical outcome.