24806-70-0

Upstream product

• 24807-13-4 N-(1-Benzoyl-2-methoxy-2-phenyl-ethyl)-benzamide 
• 24807-14-5 N-(1-Benzoyl-2-ethoxy-2-phenyl-ethyl)-benzamide 
• 17606-70-1 (4Z)-4-benzylidene-2-phenyl-1,3-oxazol-5(4H)-one 
• 26086-60-2 2-azido-4'-chloroacetophenone 
• 100-52-7 benzaldehyde 
• 26087-01-4 (Z)-2-azido-1,3-diphenylprop-2-en-1-one 
• 98-88-4 benzoyl chloride 
• 24290-58-2 trans-1,2-di-benzoyl-3-phenylaziridine 
• 7570-84-5 trans-2-phenyl-3-benzoylaziridine 
• 1361316-77-9 1,3-diphenyl-2-((triphenylphosphoranylidene)amino)prop-2-en-1-one 

Relevant academic research and scientific papers

Regio- and stereo-controlled isomerization of 1,2-diaroyl-3-aryl aziridines to the corresponding N-((Z)-1-oxo-1,3-diphenylprop-2-en-2-yl) benzamide

Regio- and stereo-controlled isomerization of 1,2-diaroyl-3-aryl aziridines to the corresponding N-((Z)-1-oxo-1,3-diphenylprop-2-en-2-yl) benzamide in the presence of diethyl thiourea in room temperature is described. A plausible mechanism has been proposed. The structures of the products were confirmed by X-ray analysis.

Regioselective and stereospecific synthesis, crystal structure and NMR assignments of N-[(Z)-1-oxo-1,3-diphenylprop-2-en-2-yl]-4-nitrobenzamide

Isomerisation of cis and trans N-acyl-2-benzoyl-3-phenylaziridines to the corresponding N-(E ) and N-[(Z )-1-oxo-1-aryl-3- phenylprop-2-en-2-yl]-4- benzamide, respectively, in the presence of diethyl thiourea is described. The structure of N-[(Z )-1-oxo- 1-phenyl-3-phenylprop-2-en-2-yl]-4-nitrobenzamide is also confirmed by the single crystal X-ray diffraction study. A mechanism for this regiospecific rearrangement is proposed.

Unexpected synthesis of 2,4,5-trisubstituted oxazoles via a tandem aza-wittig/michael/isomerization reaction of vinyliminophosphorane

2,4,5-Trisubstituted oxazoles 6 were unexpectedly prepared from a tandem reaction of vinyliminophosphorane 3 with various acyl chlorides in a one-pot fashion.