260963-53-9

Upstream product

• 111830-58-1 4-O-benzyl-1,2-dideoxy-3,6-di-O-tert-butyldimethylsilyl-2-deoxy-D-arabino-1-hexenopyranose 
• 13265-84-4 D-glucal 
• 260963-48-2 4-O-benzyl-6-O-pivaloyl-D-(+)-glucal 
• 137792-62-2 4-O-benzyl-6-O-tert-butyldimethylsilyl-D-(-)-glucal 
• 100-39-0 benzyl bromide 
• 3282-30-2 pivaloyl chloride 
• 58871-09-3 6-O-tert-butyldimethylsilyl-D-glucal 
• 58871-11-7 4-O-benzyl-D-(-)-glucal 
• 111830-53-6 1,2-dideoxy-3,6-di-O-tert-butyldimethylsilyl-2-deoxy-D-arabino-1-hexenopyranose 
• 54974-07-1 phthalimidesulfenyl chloride 
• 260963-50-6 4-O-benzyl-2-deoxy-1,3-dioxo-6-O-pivaloyl-D-(+)-glucopyranose 

Downstream Products

• 1029039-49-3 2,2-Dimethyl-propionic acid (2R,3S)-3-benzyloxy-4,6-dioxo-5-thioxo-tetrahydro-pyran-2-ylmethyl ester 
• 260963-68-6 2,2-Dimethyl-propionic acid (2R,3S,5R)-3-benzyloxy-5-(1,3-dioxo-1,3-dihydro-isoindol-2-ylsulfanyl)-4,6-dioxo-tetrahydro-pyran-2-ylmethyl ester 

Relevant academic research and scientific papers

Totally Stereoselective Synthesis of 1,3-Disaccharides through Diels-Alder Reactions

A nonclassical, totally stereoselective synthesis of orthogonally protected 1,3-disaccharides is reported. Enantiomerically pure β-keto-δ-lactones, efficiently obtained from glucal and galactal, are transformed into electron-poor heterodienes and chemo-,

A new procedure for the preparation of β-keto-δ-lactones from sugars and their transformation into glycosyl acceptors in disaccharides synthesis

(matrix presented) Glycals are effective starting materials for the synthesis of enantiopure β-ketone-δ-lactones. They are easily transformed, through a two-step, one-pot reaction, into the corresponding α,α′-dioxothiones which in turn can be quantitative