26114-89-6

Basic information

• Product Name: cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl acetate
• Synonyms: cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl acetate
• CAS NO: 26114-89-6
• Molecular Weight: 216.28
• Mol File: 26114-89-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl acetate(26114-89-6)
• EPA Substance Registry System: cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl acetate(26114-89-6)

Safety Data

• Hazardous Substances Data: 26114-89-6(Hazardous Substances Data)

Upstream product

• 26114-87-4 cis-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-ol 
• 75-36-5 acetyl chloride 
• 35376-41-1 5-phenylcyclohex-2-en-1-one 
• 493-72-1 5-phenyl-cyclohexane-1,3-dione 
• 108-24-7 acetic anhydride 

Downstream Products

• 200435-80-9 (5-ethoxy-cyclohex-3-enyl)-benzene 
• 26114-87-4 1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-ol 
• 81426-52-0 1-((1S,5R)-5-Phenyl-cyclohex-2-enyl)-propan-2-one 
• 81426-52-0 1-((1R,5R)-5-Phenyl-cyclohex-2-enyl)-propan-2-one 
• 24136-52-5 (1R,3S)-3-methyl-1,2,3,6-tetrahydro-1,1'-biphenyl 
• 24136-52-5 (1S,3R)-3-methyl-1,2,3,6-tetrahydro-1,1'-biphenyl 

Relevant articles and documents

Investigation of the aqueous transmetalation of π-allylpalladium with indium salt: The use of the Pd(OAc)2-TPPTS catalyst

π-Allylpalladium complexes could be generated in water by the palladium(0) water soluble catalyst prepared in situ from palladium acetate and TPPTS. These complexes were transmetalated with indium to react with benzaldehyde. The aqueous solution of Pd(0)(TPPTS)n could be reused without deterioration of the catalyst in the first and second recycling. The system proved to be efficient with primary and secondary allylic substrates. The stereochemical outcome of the allylation through umpolung of allylpalladium, was also studied using models with a restraint conformation. The Royal Society of Chemistry 2005.