26120-46-7

Basic information

• Product Name: ((3-fluorophenyl)methylene)bis(trimethylsilane)
• Synonyms: ((3-fluorophenyl)methylene)bis(trimethylsilane)
• CAS NO: 26120-46-7
• Molecular Weight: 254.495
• Mol File: 26120-46-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((3-fluorophenyl)methylene)bis(trimethylsilane)(CAS DataBase Reference)
• NIST Chemistry Reference: ((3-fluorophenyl)methylene)bis(trimethylsilane)(26120-46-7)
• EPA Substance Registry System: ((3-fluorophenyl)methylene)bis(trimethylsilane)(26120-46-7)

Safety Data

• Hazardous Substances Data: 26120-46-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 402-64-2 1-dichloromethyl-3-fluoro-benzene 
• 1073-06-9 3-fluorobromobenzene 
• 29955-12-2 bis(trimethylsilyl)methyl bromide 

Downstream Products

• 1644191-56-9 (E)-5-(2-fluoro-4-(3,4,5-trimethoxystyryl)phenyl)benzo[d][1,3]dioxole 
• 1644191-38-7 ((4-(benzo[d][1,3]dioxol-5-yl)-3-fluorophenyl)methylene)bis(trimethylsilane) 
• 1644191-39-8 ((3-fluoro-4-(thiophen-2-yl)phenyl)methylene)bis(trimethylsilane) 

Relevant articles and documents

Preparation and regioselective metalation of Bis(trimethylsilyl)methyl- substituted aryl derivatives

A range of bis(trimethylsilyl)methyl-substituted aryl derivatives was prepared by using a Kumada-Corriu cross-coupling reaction. The regioselective metalation of the resulting bis(trimethylsilyl)methyl-substituted aryl derivatives bearing this bulky silyl group allowed the generation of functionalized aromatics. A regioselective switch in the presence or in the absence of the bis(trimethylsilyl)methyl group has been demonstrated. Furthermore, this silyl group was converted into a formyl group or a styryl group, enhancing the scope of application of such bis(trimethylsilyl)methyl- substituted arenes.