402-64-2

Basic information

• Product Name: 3-FLUOROBENZAL CHLORIDE
• Synonyms: M-FLUOROBENZAL CHLORIDE;1-DICHLOROMETHYL-3-FLUOROBENZENE;A,A-DICHLORO-3-FLUOROTOLUENE;3-FLUOROBENZAL CHLORIDE;3-Fluorobenzalchloride,98%;à,à-dichloro-3-fluorotoluene;3-Fluorobenzal chloride 98%;3-Fluoro-1-dichloromethylbenzene
• CAS NO: 402-64-2
• Molecular Formula: C₇H₅Cl₂F
• Molecular Weight: 179.02
• EINECS: 206-952-5
• Mol File: 402-64-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 195 °C
• Flash Point: 195-197°C
• Appearance: /
• Density: 1.341g/cm³
• Refractive Index: 1.5275
• Sensitive: Lachrymatory
• BRN: 1936379
• CAS DataBase Reference: 3-FLUOROBENZAL CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-FLUOROBENZAL CHLORIDE(402-64-2)
• EPA Substance Registry System: 3-FLUOROBENZAL CHLORIDE(402-64-2)

Safety Data

• Hazard Codes: C
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-45
• RIDADR: 3265
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 402-64-2(Hazardous Substances Data)

Usage

General Description

3-Fluorobenzal chloride is a chemical compound with the molecular formula C7H4ClFO. It is a colorless to pale yellow liquid that is primarily used as an intermediate in the production of pharmaceuticals and agrochemicals. 3-FLUOROBENZAL CHLORIDE is also utilized in the synthesis of various organic compounds, including dyes, pigments, and polymers. 3-Fluorobenzal chloride is a reactive compound that is highly corrosive and toxic and should be handled with extreme caution. It is typically stored and handled in a well-ventilated area, away from heat, sparks, and open flame.

InChI:InChI=1/C7H5Cl2F/c8-7(9)5-2-1-3-6(10)4-5/h1-4,7H

Upstream product

• 456-42-8 m-fluorobenzyl chloride 
• 1333429-12-1 3-fluorobenzyl trimethylsilyl ether 
• 18539-43-0 2-<3-Fluor-benzyloxy>-tetrahydro-pyran 
• 401-77-4 3-fluoro-1-(trichloromethyl)benzene 
• 352-70-5 m-Fluorotoluene 
• 456-48-4 3-Fluorobenzaldehyde 
• 456-47-3 3-fluoro-benzenemethanol 

Downstream Products

• 455-34-5 1-(dibromomethyl)-3-fluorobenzene 
• 456-48-4 3-Fluorobenzaldehyde 
• 26120-46-7 ((3-fluorophenyl)methylene)bis(trimethylsilane) 
• 3094-46-0 5-Fluor-2-nitrobenzaldehyd-diacetat 
• 716-67-6 5-Fluor-2,ω-dinitro-styrol 
• 720-22-9 1-<5-Fluor-2-nitrophenyl>-2-nitro-ethanol 
• 395-81-3 5-fluoro-2-nitrobenzaldehyde 

Relevant articles and documents

REDUKTION VON BENZOTRICHLORIDEN ZU BENZALCHLORIDEN

Benzal chlorides are prepared from the corresponding benzotrichlorides by reduction with thiophenol in the presence of catalytic amounts of copper(I) bromide.

One-pot, selective and mild conversion of benzylic alcohols to gem -dichlorides using chlorodiphenylphosphine and 2,3-dichloro-5,6-dicyanobenzoquinone as a new and neutral system

A mild and one-pot conversion of benzylic alcohols to their corresponding gem-dichlorides is reported for the first time using chlorodiphenylphosphine (ClPPh2) and 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) in dichloromethane under neutral conditions and at room temperature. The present method can be efficiently used for preparation of gem-dichlorides even in the presence of some other functional groups with excellent chemoselectivity.

MECHANISMS OF FREE-RADICAL REACTIONS. XIII. MECHANISM AND SELECTIVITY OF THE FREE-RADICAL HALOGENATION OF ALKYL AROMATIC HYDROCARBONS WITH FLUOROALKYL SUBSTITUENTS

The free-radical chlorination and bromination of 1-fluoro-2-arylethanes and 1,1,1-trifluoro-2-arylethanes was studied by the method of competing reactions.In all cases a good correalation between log krel and the Brown ?+ constants was observed.The variation of the selectivity in the transition from one reaction series to the other indicates that two independent factors which determine the reactivity (the change in the dissociation energy of the C-H bond and the polar effect of the substituents) have a simultaneous effect.