26210-60-6

Basic information

• Product Name: Silanamine, N,N-diethyl-1,1-dimethyl-1-phenyl-
• Synonyms: N,N-diethyl-1,1-dimethyl-1-phenylsilylamine;[dimethyl(phenyl)silyl]diethylamine;Silanamine,N,N-diethyl-1,1-dimethyl-1-phenyl;Diaethylamino-phenyl-dimethylsilan;diethylamino-diethyl-phenyl-silane;Diethylaminodimethylphenylsilane
• CAS NO: 26210-60-6
• Molecular Formula: C12H21NSi
• Molecular Weight: 207.391
• Mol File: 26210-60-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silanamine, N,N-diethyl-1,1-dimethyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N,N-diethyl-1,1-dimethyl-1-phenyl-(26210-60-6)
• EPA Substance Registry System: Silanamine, N,N-diethyl-1,1-dimethyl-1-phenyl-(26210-60-6)

Safety Data

• Hazardous Substances Data: 26210-60-6(Hazardous Substances Data)

Upstream product

• 100-58-3 phenylmagnesium bromide 
• 766-77-8 Dimethylphenylsilane 
• 109-89-7 diethylamine 
• 768-33-2 phenyldimethylsilyl chloride 

Downstream Products

• 79628-15-2 dimethyl(phenyl)(phenylethynyl)silane 

Relevant articles and documents

Mechanistic Insights on the Functionalization of CO2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate-Functionalized Bis-NHC Catalyst

The zwitterionic complex [Cp*IrCl{(MeIm)2CHCOO}] (1) efficiently catalyzes the selective hydrosilylation of CO2 to afford the corresponding silylformate. The best reaction performance has been achieved in acetonitrile at 348 K using HSiMe2Ph. The 1-catalyzed reaction of pyrrolidine with CO2 and HSiMe2Ph strongly depends on the CO2 pressure. At low concentration of CO2 (1 bar) formation of the corresponding silylcarbamate, by insertion of CO2 into the Si?N bond of the in situ generated silylamine was observed, while at higher pressure (3 bar) the formamide derivative was obtained as major reaction product. The unexpected formation of pyrrolidin-1-ium formate as intermediate of the reaction the 1-catalyzed of CO2 with pyrrolidine and HSiMe2Ph has been observed, and its role in the formation of 1-formylpyrrolidine rationalized. Moreover, a mechanism for the reaction of CO2 with hydrosilanes, in the presence and in the absence of amines, based on theoretical calculations has been proposed.

Aminosilylation of arynes with aminosilanes: Synthesis of 2-silylaniline derivatives

The nitrogen-silicon σ-bond of aminosilanes added across the triple bond of arynes to give varied 2-silylaniline derivatives straightforwardly. The Royal Society of Chemistry 2005.

Process for preparing polyisocyanato/polyisocyanurates by catalytic cyclotrimerization of polyisocyanates

Polyisocyanurate/polyisocyanates of enhanced stability are prepared by partial catalytic cyclotrimerization of a polyisocyanate in the presence of a catalytically effective amount of an aminosilyl catalyst and wherein the cyclotrimerization reaction is terminated when a predetermined desired amount of isocyanurate groups has been attained, by adding to the reaction mixture, after the cooling thereof to a temperature of below 50° C., a reaction terminating amount of an organic catalyst deactivating compound comprising at least one free hydroxyl moiety, or the reaction product of such hydroxylated organic catalyst deactivating compound with an isocyanate.