26256-87-1Relevant articles and documents
Sulfurization of polymers 1. The reaction of polydialkylsiloxanes with elemental sulfur and electrochemical behavior of the products
Trofimov, B. A.,Skotheim, T. A.,Parshina, L. N.,Khil'ko, M. Ya.,Oparina, L. A.,Kovalev, L. P.,Gavrilov, A. B.
, p. 463 - 469 (1999)
The hydrosilylation of vinyl methyl and divinyl ethers of oligoethylene glycols with polyhydridosiloxanes in the presence of chloroplatinic acid is accompanied by side processes, namely, polymerization of vinyl ethers and homodehydrocondensation of polyhydridosiloxanes. The electrical conductivity of ca. 1 M solutions of lithium triflate or bis(trifluoromethylsulfonyl) imide in the resulting hydrosilylation products is ca. 10-5 S cm-1.
Vinyl polymerization versus [1,3] O to C rearrangement in the ruthenium-catalyzed reactions of vinyl ethers with hydrosilanes
Harada, Nari-Aki,Nishikata, Takashi,Nagashima, Hideo
supporting information; experimental part, p. 3243 - 3252 (2012/06/01)
Two reactions, vinyl polymerization and [1,3] O to C rearrangement of vinyl ethers, are investigated in the ruthenium-catalyzed reaction with hydrosilanes. The reaction pathways are dependent on the substituents of the vinyl ether, in particular, those of the alkoxy group. Primary-, secondary-, and tertiary-alkyl vinyl ethers, ROCHCH2, are polymerized with ease to give the corresponding polymer in good yields. When R is electron-donating benzyl groups, the reaction does not give the polyvinyl ether but results in [1,3] O to C rearrangement to give the corresponding aldehyde, RCH2CHO in moderate to good yields. The rearrangement selectively proceeds when vinyl ethers having α-substituents are used as the starting materials to give the corresponding ketones in high yields. With catalytic amounts of hydrosilanes, the rearrangement gives ketones or aldehydes selectively. In sharp contrast, use of excess amounts of hydrosilanes leads to the rearrangement followed by reduction of the formed carbonyl group to give the corresponding silyl ethers in good yields. Nature of catalytically active species is discussed. Crown Copyright
