26257-80-7Relevant academic research and scientific papers
Chemoselective in situ Protection of Aldehydes and Ketones using Titanium Tetrakis(dialkylamides)
Reetz, Manfred T.,Wenderoth, Bernd,Peter, Roland
, p. 406 - 408 (2007/10/02)
Titanium tetrakis(dialkylamides) are chemoselective protective agents for carbonyl compounds, so that such reactions as Grignard and aldol additions can be induced to occur at ketone groups in the presence of aldyhydes in a one-pot precedure.
Glycol Ester Formation in the Reformatsky Reaction
Plattner, Jacob J.,Gawronska, Eva,Rinehart, Kenneth L.
, p. 3440 - 3442 (2007/10/02)
A previously unrecognized side reaction in the Reformatsky reaction has been identified in the reaction of heptanal with ethyl bromoacetate.The products are derived from the two isomeric heptanoates of the glycol 2-pentyl-3-hydroxynonanol, formed from 3 mol of heptanal under the presumed catalysis of the bromo zinc enolate.
