26279-24-3Relevant academic research and scientific papers
Strain and hueckel aromaticity: Driving forces for a promising new generation of electron acceptors in organic electronics
Brunetti,Gong,Tong,Heeger,Wudl, Fred
, p. 532 - 536 (2010)
(Figure Presented) Straining at the leash: The main features of electron-accepting materials with a 9,9′-bifluorenylidene backbone are strain relief and a gain in aromaticity. These dimers (see picture) exhibit absorption near the red spectral region (ca. 600 nm) and HOMO (5.58-5.06 eV) and LUMO (3.37-3.09 eV) energy levels, which, together with high solubility and thermal stability render these materials attractive acceptors for bulk heterojunction (BHJ) solar cells.
Synthesis and photovoltaic properties of polymeric metal complexes containing 8-hydroxyquinoline as dye sensitizers for dye-sensitized solar cells
Zhang, Lirong,Wen, Gaojun,Xiu, Qian,Guo, Lihui,Deng, Jinyan,Zhong, Chaofan
, p. 1632 - 1644 (2012/06/01)
Four new donor-acceptor type polymeric metal complexes (P1, P2, P3, and P4) with the same Cd(II) complex in side chain and different conjugated backbone structures were synthesized by Yamamoto coupling and applied in dye-sensitized solar cells (DSSCs) as photosensitizers. The photophysical, electrochemical, and thermal properties were investigated in detail, showing that conjugated backbone containing fluorene improved intramolecular charge transfer and increased generation of photocurrent. The highest power conversion efficiency of 0.56% (J sc=1.63mAcm2, V oc=0.69V, FF=0.50) was obtained with a DSSC based on P3 under simulated air mass 1.5 G solar irradiation, which shows a new strategy to design photosensitizers for DSSCs.
