263011-57-0

Basic information

• Product Name: (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde
• Synonyms: (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde
• CAS NO: 263011-57-0
• Molecular Weight: 220.268
• Mol File: 263011-57-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde(263011-57-0)
• EPA Substance Registry System: (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde(263011-57-0)

Safety Data

• Hazardous Substances Data: 263011-57-0(Hazardous Substances Data)

Upstream product

• 81520-03-8 (2E,4R)-5-(benzyloxy)-4-methyl-2-penten-1-ol 
• 81520-05-0 [(2R,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 

Downstream Products

• 69056-12-8 (+)-Prelog-Djerassi lactonic acid 
• 144606-47-3 (2R,4S,5S,6S)-7-benzyloxy-5-hydroxy-2,4,6-trimethylheptanoic acid δ-lactone 
• 263011-62-7 (Z)-4-[(4S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid ethyl ester 
• 263011-60-5 ethyl {(4R,6S)-6-[(S)-2-(benzyloxy)-1-methylethyl]-2-phenyl-1,3-dioxan-4-yl}acetate 
• 263011-61-6 [(4R,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2-phenyl-[1,3]dioxan-4-yl]-acetaldehyde 
• 263011-63-8 (S)-6-((2S,3S)-4-Benzyloxy-2-hydroxy-3-methyl-butyl)-5,6-dihydro-pyran-2-one 
• 263011-66-1 (2S,3S)-4-Benzyloxy-1-((S)-6-methoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-butan-2-ol 
• 263011-59-2 ethyl (E)-(5S,6S)-7-(benzyloxy)-5-hydroxy-6-methylhept-2-enoate 
• 263011-58-1 (3S,4S)-5-Benzyloxy-3-hydroxy-4-methyl-pentanal 
• 142997-96-4 (E)-3-[(2R,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-2-methyl-acrylic acid ethyl ester 

Relevant articles and documents

An efficient and stereoselective construction of the C(9)-C(17) dihydropyran segment of swinholides A-C via a novel reductive cleavage of an epoxy aldehyde

An efficient and highly stereoselective construction of the C(9)-C(17) dihydropyran segment of swinholides A-C, which involves a novel reductive cleavage of an epoxy aldehyde by an organoselenium reagent and the intramolecular conjugate addition of an ace

Synthesis of the Prelog-Djerassi Lactone and Protomycinolide IV Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum

The Prelog-Djerassi lactone, a key intermediate for the synthesis of several medicinally important macrolide antibiotics, and protomycinolide IV, a 16-membered macrolide, have been synthesized by employing the recently developed stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum as key steps.