81520-05-0

Upstream product

• 81520-03-8 (2E,4R)-5-(benzyloxy)-4-methyl-2-penten-1-ol 
• 73814-74-1 (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-en-1-ol 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 81470-72-6 (R)-ethyl (Z)-5-benzyloxy-4-methyl-2-pentenoate 
• 81470-75-9 (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester 
• 74130-31-7 3-(benzyloxy)-2-methylpropanal 
• 100-39-0 benzyl bromide 
• 81470-71-5 ((S)-3-tert-Butoxy-2-methyl-propoxymethyl)-benzene 
• 81520-06-1 ((R)-4,4-Dibromo-2-methyl-but-3-enyloxymethyl)-benzene 
• 81470-74-8 (R)-5-Benzyloxy-4-methyl-pent-2-ynoic acid methyl ester 
• 81470-73-7 ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate 
• 104265-23-8 (2R,S)-((2S)-3-benzyloxy-2-methylpropoxy)tetrahydropyran 
• 74924-27-9 methyl (S)-3-benzyloxy-2-methylpropanoate 

Downstream Products

• 263011-57-0 (2S,3R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane-2-carbaldehyde 
• 107093-42-5 (3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol 
• 618096-09-6 (2S,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxirane-2-carbaldehyde 
• 1354396-76-1 (S)-1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol 
• 1354396-77-2 (R)-1-[(2R,3S)-3-((S)-2-benzyloxy-1-methylethyl)oxiranyl]-3-(triisopropylsilyl)prop-2-yn-1-ol 
• 108393-28-8 (2S,3R,4S)-5-benzyloxy-2,3-dimethylpentane-1,4-diol 
• 110410-36-1 Acetic acid (1R,2R)-2,3-diacetoxy-1-((R)-2-benzyloxy-1-methyl-ethyl)-propyl ester 
• 108393-30-2 (2R,3R,4R)-5-(benzyloxy)-2,4-dimethyl-1,3-pentanediol 
• 81520-10-7 (2S,3S,4S)-5-Benzyloxy-2,4-dimethylpentan-1,3-diol 
• 83458-89-3 (3R,4S)-5-Benzyloxy-4-methyl-pentane-1,3-diol 
• 83458-90-6 (2R,4R)-5-Benzyloxy-4-methyl-pentane-1,2-diol 
• 81520-11-8 (2R,3S,4S)-5-(benzyloxy)-2,4-dimethylpentane-1,3-diol 
• 137433-86-4 (2R,3R,4R)-5-Benzyloxy-3,4-dimethyl-pentane-1,2-diol 
• 618096-11-0 2,2-Dimethyl-propionic acid (2S,3S,4S,5S,6S)-7-benzyloxy-3-hydroxy-2,4,6-trimethyl-5-triethylsilanyloxy-heptyl ester 

Relevant academic research and scientific papers

Catalytic diastereoselective reduction of α,β-epoxy and α,β-aziridinyl ynones

The Noyori transfer hydrogenation of α,β-epoxy and α,β-aziridinyl ynones leads to the corresponding α,β-epoxy or α,β-aziridinyl propargylic alcohols with high reagent-controlled diastereoselectivity.

Total synthesis of scytophycin C. 1. Stereoselective syntheses of the C(1)-C(18) segment and the C(19)-C(31) segment

[Equation presented] Stereoselective total synthesis of scytophycin C, a marine 22-membered macrolide displaying potent activity against a variety of human carcinoma cell lines, has been reported in which the polypropionate structure bearing contiguous as

An efficient and stereoselective construction of the C(9)-C(17) dihydropyran segment of swinholides A-C via a novel reductive cleavage of an epoxy aldehyde

An efficient and highly stereoselective construction of the C(9)-C(17) dihydropyran segment of swinholides A-C, which involves a novel reductive cleavage of an epoxy aldehyde by an organoselenium reagent and the intramolecular conjugate addition of an ace

Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins

A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed

Pheromone Synthesis, CXXXV. Synthesis of (4R,5R,6S,7E,9E)-4,6,8-Trimethyl-7,9-undecadien-5-ol and Its Antipode, the Female Specific Compound of the Woodroach Cryptocercus punctulatus

(4R,5R,6S,7E,9E)-4,6,8-Trimethyl-7,9-undecadien-5-ol (1) and its antipode 1', the female specific compound of the woodroach Cryptocercus punctulatus, were synthesized by starting from methyl (R)-3-hydroxy-2-methylpropanoate (C). Key Words: Chiral centers,

NEW ALLYLSTANNANES FOR THE CONNECTIVE CONSTRUCTION OF MONOPROTECTED VICINAL DIOLS

The preparation of allylstannanes 1a-c, all of which bear an oxygen substituent at the allylic terminus, is desribed.These reagents react with alpha- and beta-alkoxyaldehydes in the presence of MgBr2 as Lewis acid to give SE' products with diastereofacial selectivity consistent with "chelation control"; a syn disposition of substituents about the newly formed bond is highly favored in all cases.