26524-38-9

Basic information

• Product Name: Benzene, (1-chloro-2-methyl-1-propenyl)-
• CAS NO: 26524-38-9
• Molecular Formula: C10H11Cl
• Molecular Weight: 166.65
• Mol File: 26524-38-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, (1-chloro-2-methyl-1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-chloro-2-methyl-1-propenyl)-(26524-38-9)
• EPA Substance Registry System: Benzene, (1-chloro-2-methyl-1-propenyl)-(26524-38-9)

Safety Data

• Hazardous Substances Data: 26524-38-9(Hazardous Substances Data)

Upstream product

• 611-70-1 phenyl isopropyl ketone 
• 75-44-5 phosgene 
• 7473-99-6 α-chloroisobutyrophenone 
• 4850-86-6 1,1-dichloro-2-methyl-2-phenylpropane 
• 2882-19-1 ethyl 2-phenyl-2-bromoacetate 
• 4593-90-2 3-phenylbutyric acid 
• 173033-90-4 Phenyl-(propane-2-sulfonyl)-acetic acid ethyl ester 
• 34009-00-2 benzyl isopropyl sulfone 
• 36318-77-1 [1-(dichloromethyl)-1-methylpropyl]benzene 

Downstream Products

• 53546-24-0 3-Phenyl-4-methyl-3-penten-2-ol 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 29817-09-2 1-methylene-2-phenylcyclopropane 
• 7473-99-6 α-chloroisobutyrophenone 
• 79913-31-8 1,1,2-trichloro-2-phenyl-3,3-dimethylcyclopropane 
• 53546-26-2 4-methyl-3-phenyl-3-penten-2-one 
• 29689-80-3 3-methyl-1,2-diphenylbut-2-en-1-one 
• 53546-25-1 1,2-Diphenyl-3-methyl-2-buten-1-ol 

Relevant articles and documents

FIRST DETERMINATION OF AN ABSOLUTE RATE CONSTANT FOR A 1,2-PHENYL MIGRATION TO A CARBENE

The first determination of a 1,2-phenyl shift in α,α-dimethylbenzylchlorocarbene was achieved by nanosecond laser flash photolysis, τ = 50 ns.

Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism

An unprecedented iodine(III)-mediated oxidative transposition of vinyl halides has been accomplished. The products obtained, α-halo ketones, are useful and polyvalent synthetic precursors. There are only a handful of reported examples of the direct conversion of vinyl halides to their corresponding α-halo carbonyl compounds. Insights into the mechanism and demonstration that this synthetic transformation can be done under enantioselective conditions are reported.

Novel reaction: Decarboxylative Bamberg-Backlung rearrangement in some α-isopropyl sulfonyl carboxylic esters

The reaction of some isopropylsulfonyl α-mono and disubstituted esters with KOH/t-BuOH/CCl4 is reported. For the α,α-dialkyl and α-monoaryl substituted derivatives the key step of this reaction is proposed to be the decarboxylative 1,3-displacement in the chlorinated intermediates.