26540-44-3Relevant articles and documents
Synthesis of 1,6-Anhydro-2-chloro-2,3,4-trideoxy-β-D-erythro-hex-3-enopyranose and its Stereospecific SN2' Substitution
Matsumoto, Masakatsu,Ishikawa, Hiromi,Soya, Yoshihiro,Ozawa, Takayuki
, p. 2377 - 2382 (2007/10/02)
The chlorination of 1,6-anhydro-3,4-dideoxy-β-D-threo-hex-3-enopyranose (2) with SOCl2 and pyridine gives predominantly 1,6-anhydro-2-chloro-β-D-erythro-hex-3-enopyranose (3).The chloride (3) takes place exclusively the suprafacial SN2' substit
SYNTHESES OF 3-DEOXY-3-SUBSTITUTED-D-GLUCOSE DERIVATIVES. PART I. IMPROVEMENTS IN PREPARATION OF AND NUCLEOPHILIC ADDITIONS TO 1,6:2,3-DIANHYDRO-4-O-BENZYL-Β-D-ALLOPYRANOSE
Grindley, Bruce T.,Reimer, Gerry J.,Karlovec, Jaroslav,Brown, Robert G.,Andersob, Max
, p. 1065 - 1071 (2007/10/02)
The yield of the five-step preparation of 1,6:2,3-dianhydro-4-O-benzyl-β-D-glucopyranose from 1,6-anhydro-β-D-glucopyranose has been raised to 33percent from 12percent by modifying conditions or methods for four of the steps.It has been demonstrated that