26540-43-2

Basic information

• Product Name: 1,6-anhydro-4-O-benzyl-3-O-methanesulfonyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose
• Synonyms: 1,6-anhydro-4-O-benzyl-3-O-methanesulfonyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose
• CAS NO: 26540-43-2
• Molecular Weight: 484.548
• Mol File: 26540-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,6-anhydro-4-O-benzyl-3-O-methanesulfonyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-anhydro-4-O-benzyl-3-O-methanesulfonyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose(26540-43-2)
• EPA Substance Registry System: 1,6-anhydro-4-O-benzyl-3-O-methanesulfonyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose(26540-43-2)

Safety Data

• Hazardous Substances Data: 26540-43-2(Hazardous Substances Data)

Upstream product

• 498-07-7 levoglucosan 
• 20183-65-7 1,6-anhydro-4-O-benzyl-2-O-(4-toluenesulfonyl)-β-D-glucopyranose 
• 124-63-0 methanesulfonyl chloride 
• 6167-32-4 1,6:3,4-dianhydro-2-O-tosyl-D-galactose 
• 100-51-6 benzyl alcohol 
• 20204-80-2 [(1R,2S,3S,4R,5R)-3-hydroxy-4-(p-tolylsulfonyl)-6,8-dioxabicyclo[3.2.1]oct-2-yl]-4-methylbenzenesulfonic acid 

Downstream Products

• 26540-44-3 4-O-benzyl-1,6:2,3-dianhydro-β-D-allopyranoside 
• 112233-71-3 2-O-acetyl-4-C-(acetoxyphenylmethyl)-1,6-anhydro-3,4-dideoxy-β-D-glucopyranose 
• 112233-67-7 1,6-anhydro-4-O-benzyl-3-deoxy-3-ethylthio-β-D-glucopyranose 
• 112233-65-5 1,6-anhydro-4-O-benzyl-3-cyano-3-deoxy-β-D-glucopyranose 
• 112233-68-8 1,6-anhydro-4-O-benzyl-3-deoxy-3-methylamino-β-D-glucopyranose 
• 112233-66-6 1,6-anhydro-4-O-benzyl-3-deoxy-3-methylthio-β-D-glucopyranose 
• 112233-63-3 1,6-anhydro-4-O-benzyl-3-chloro-3-deoxy-β-D-glucopyranose 
• 112233-64-4 1,6-anhydro-4-O-benzyl-3-deoxy-3-fluoro-β-D-glucopyranose 
• 112233-69-9 1,6-anhydro-4-O-benzyl-3-deoxy-3-C-methyl-β-D-glucopyranose 

Relevant articles and documents

Synthesis of Protected 3-Deoxy-3-fluoro- and 4-Deoxy-4-fluoro-d-galactopyranosides from Levoglucosan

Fluorinated carbohydrates are invaluable tools to study various biochemical processes. Herein, we describe a new strategy to access orthogonally protected 3-deoxy-3-fluorogalactopyranose and acetylated 4-deoxy-4-fluorogalactopyranose. Starting from inexpensive levoglucosan, most reactions were performed on a gram scale and allowed excellent regio- and stereocontrol with a minimal use of protection/deprotection cycles. Hence, we developed practical alternatives to the decade-long reported method to access both 3-deoxy-3-fluoro- and 4-deoxy-4-fluorogalactopyranose.