26549-63-3Relevant academic research and scientific papers
Synthese de phosphinites derives de sucres: applications en cyclodimerisation du penta 2,4-dienoate de methyle, en hydrogenation et en hydrosilylation de la pentolactone
Bendayan, Andree,Masotti, Henriette,Peiffer, Gilbert,Siv, Chhan,Archavlis, Albert
, p. 41 - 46 (2007/10/02)
Sugar-derived phosphinites, when used as ligands in the catalytic hydrogenation of α-ketopentolactone, lead to the corresponding alcohol with a better enantiomeric excess (20percent) than in hydrosilylation (10percent).In the cyclodimerisation of penta-2,4-dienoic acid methyl ester they lead to the meso cycloocta-3,7-diene-1,2-doic dimethyl ester.
Organometallic Compounds in Organic Synthesis. Part 13. Stereoselectivity of Complexation of Cyclohexadiene Esters
Bandara, B. M. Ratnayake,Birch, Arthur J.,Raverty, Warwick D.
, p. 1755 - 1762 (2007/10/02)
Complexation of cyclohexadienes with Fe(CO)3 as the entering group are subject to classical steric hindrance by alkyl groups, but CO2R and related groups introduce a competing factor because they favour sterically the entering group, probably through an i
Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, V. 1,3-Cyclohexadiene-5,6-dicarboxylic Acid Derivatives as Reactants
Kresze, Guenter,Kysela, Ernst,Dittel, Werner
, p. 210 - 223 (2007/10/02)
The use of 1,3-cyclohexadiene-5,6-dicarboxylic acid derivatives as educts for the reaction sequence: Diels-Alder reaction with nitroso compounds, reduction of the adducts, hydroxylation, gives hexa-substituted cyclohexanes.However, attempts to synthesize
