265648-84-8

Upstream product

• 103723-91-7 cinnamyl chloroformate 
• 104-54-1 3-Phenylpropenol 
• 14435-92-8 carbonyl azide 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 1345964-29-5 (5S,6R)-6-phenyl-3-oxa-1-azabicyclo[3.1.0]hexan-2-one 
• 1424055-47-9 C₁₀H₉NO₂ 
• 1345964-30-8 (R)-4-[(S)-methoxy(phenyl)methyl]oxazolidin-2-one 
• 169532-08-5 (1α,5α)-6β-phenyl-3-oxabicyclo[3.1.0]hexan-2-one 
• 132435-61-1 (1α,5α)-6β-phenyl-3-oxabicyclo[3.1.0]hexan-2-one 

Relevant academic research and scientific papers

Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis

Cobalt(II)-based metalloradical catalysis has been successfully applied to radical bicyclization of allyl azidoformates to construct aziridine/oxazolidinone-fused bicyclic structures. The Co(II) complex of D2-symmetric chiral amidoporphyrin 3,5

A facile synthesis of azidoformate via chloroformate

This work synthesized chloroformates by slowly adding alcohols into a suspension of trichloromethyl chloroformate, instead of phosgene, along with activated charcoal in tetrahydrofuran. This chloroformylation yielded chloroformates in near quantitative yield. The subsequent reaction between chloroformates and sodium azide in dry acetone produced azidoformates in a high yield.