2657-10-5Relevant academic research and scientific papers
Mild, efficient friedel-Crafts acylations from carboxylic acids using cyanuric chloride and AlCl3
Kangani, Cyrous O.,Day, Billy W.
supporting information; experimental part, p. 2645 - 2648 (2009/05/27)
(Chemical Equation Presented) A mild method for Friedel-Crafts acylation with aromatic and aliphatic carboxylic acids using cyanuric chloride, pyridine, and AlCl3 was developed. Both inter- and intramolecular acylations were achieved at room temperature in high yield and in very short reaction times.
SYNTHESE ET ETUDE DE LA DEGRADATION PHOTOCHIMIQUE DE TENSIO-ACTIFS CATIONIQUES PHOTOCLIVABLES
Strub-Leconte, M. P.,Riess, G.
, p. 137 - 144 (2007/10/02)
A homologous series of photocleavable cationic surfactants was prepared.These aryl-alkyl-ketone type surfactants have the following structure .Their critical micelle concentration in water was determined.The photodegradation study has shown that the cleavage occurs with a high quantum yield by a Norrish II mechanism with formation of alkene, substituted acetophenone and cyclobutanols.The photochemical yield of cleavage reaches 75 percent with formation of a hydrophilic (substituted acetophenone) and a hydrophobic derivative (alkene).
